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kicyunya [14]
3 years ago
8

For the gas phase decomposition of nitrosyl chloride at 400 K , the rate of the reaction is determined by measuring the appearan

ce of Cl2 . 2 NOCl= 2 NO + Cl2 At the beginning of the reaction, the concentration of Cl2 is 0 M. After 1.64×103 min the concentration has increased to 3.39×10-3 M. What is the rate of the reaction?
Chemistry
1 answer:
UkoKoshka [18]3 years ago
5 0

Answer:

2.067 x 10⁻⁷ M/min.

Explanation:

  • Knowing that the rate of the reaction is the change in the concentration of reactants (decrease) or the products (increase) with time.

  • For the reaction: <em>2NOCl ⇄ 2NO + Cl₂,</em>

<em>Rate of the reaction = - 1/2 d[NOCl]/dt = 1/2 d[NO]/dt = d[Cl₂]/dt</em>

∵ d[Cl₂] = 3.39 x 10⁻³ M, dt = 1.64 x 10³ min.

∴ Rate of the reaction = d[Cl₂]/dt = (3.39 x 10⁻³ M) / (1.64 x 10³ min) = 2.067 x 10⁻⁷ M/min.

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it takes 463 kJ/mol to break an oxygen-hydrogen single bond. calculate the maximum wavelength of light for which an oxygen-hydro
Marianna [84]

Answer:

  • <u>2.59 × 10⁻⁷ m  = 259 nm</u>

Explanation:

You need to calculate the wavelength of a photon with an energy equal to 463 kJ/mol, which is the energy to break an oxygen-hydrogen atom.

The energy of a photon and its wavelength are related by the Planck - Einstein equation:

  • E = hν,

Where:

  • E = energy of a photon,
  • h = Planck constant (6.626 × 10⁻³⁴ J . s) and
  • ν = frequency of the photon.

And:

  • ν = c / λ

Where:

  • c = speed of light (3.00 × 10⁸ m/s in vacuum)
  • λ = wavelength of the photon

Thus, you can derive:

  • E = h c / λ

Solve for λ:

  • λ = h c / E

Before substituting the values, convert the energy, 463 kJ/ mol, to J/bond

  • 463 kJ/ mol × 1,000 J/kJ × 1 mol / 6.022 × 10 ²³ atom × 1 bond / atom

       = 7.69×10²³ J / bond

Substitute the values and use the energy of one bond:

  • λ = 6.626 × 10⁻³⁴ J . s × 3.00 × 10⁸ m/s / 7.69×10²³ J = 2.59 × 10⁻⁷ m

The wavelength of light is usually shown in nanometers:

  • 2.59 × 10⁻⁷ m × 10⁹ nm / m = 259 nm ← answer
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