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Aleonysh [2.5K]
3 years ago
7

Be sure to answer all parts.The equilibrium constant (Kc) for the formation of nitrosyl chloride, an orange-yellow compound, fro

m nitric oxide and molecular chlorine 2NO(g) + Cl2(g) ⇌ 2NOCl(g) is 1 × 107 at a certain temperature. In an experiment, 4.40 × 10−2 mole of NO, 1.80 × 10−3 mole of Cl2, and 9.50 moles of NACl are mixed in a 2.60−L flask. What is Qc for the experiment
Chemistry
1 answer:
miss Akunina [59]3 years ago
7 0

Explanation:

Since, the given reaction is as follows.

       2NO(g) + Cl_{2} \rightleftharpoons 2NOCl

Expression for Q_{c} of this reaction is as follows.

       Q_{c} = \frac{[NOCl]^{2}}{[NO]^{2}[Cl_{2}]}

Putting the given values into the above formula as follows.

       Q_{c} = \frac{[NOCl]^{2}}{[NO]^{2}[Cl_{2}]}

               = \frac{(9.50)^{2}}{(4.40 \times 10^{-2})^{2} \times (1.80 \times 10^{-3})}

               = \frac{90.25}{34.848 \times 10^{-7}}

              = 2.59 \times 10^{-7}

Thus, we can conclude that Q_{c} for the experiment is 2.59 \times 10^{-7}.

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A 0.04328 g sample of gas occupies 10.0-mL at 294.0 K and 1.10 atm. Upon further analysis, the compound is found to be 25.305% C
stepan [7]

Answer:

<u>The molecular formula of the gas sample = C_2Cl_2 </u>

<u>Lewis structure is shown in the image below.</u>

<u>The geometry around each carbon atom is linear.</u>

Explanation:

Given that:

Temperature = 294.0 K

V = 10.0 mL = 0.01 L ( 1 mL = 0.001 L )

Pressure = 1.10 atm

Using ideal gas equation as:

PV=nRT

where,  

P is the pressure

V is the volume

n is the number of moles

T is the temperature  

R is Gas constant having value = 0.0821 L atm/ K mol  

Applying the equation as:

1.10 atm × 0.01 L = n ×0.0821 L atm/ K mol  × 294.0 K  

⇒n = 0.0004557 mol

Given, mass = 0.04328 g

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Thus,

0.0004557\ mole= \frac{0.04328\ g}{Molar\ mass}

<u>Molar mass of the gas sample = 94.9747 g/mol</u>

Given that:-

% of C = 25.305

Molar mass of C = 12.0107 g/mol

% moles of C = 25.305 / 12.0107 = 2.1069

% of Cl = 74.695

Molar mass of Cl = 35.453 g/mol

% moles of Cl = 74.695 / 35.453 = 2.1069

Taking the simplest ratio for C and Cl as:

2.1069 : 2.1069  = 1 : 1

<u>The empirical formula is = CCl</u>

Molecular formulas is the actual number of atoms of each element in the compound while empirical formulas is the simplest or reduced ratio of the elements in the compound.

Thus,  

Molecular mass = n × Empirical mass

Where, n is any positive number from 1, 2, 3...

Mass from the Empirical formula = 12 + 35.5 = 47.5 g/mol

Molar mass = 94.9747 g/mol

So,  

Molecular mass = n × Empirical mass

94.9747 = n × 47.5

⇒ n = 2

<u>The molecular formula of the gas sample = C_2Cl_2 </u>

Also,

Valence electrons of carbon = 4

Valence electrons of Chlorine = 7  

The total number of the valence electrons  = 4*2 + 7*2 = 22

The Lewis structure is drawn in such a way that the octet of each atom in the molecule is complete. So,  

The Lewis structure is shown in the image below.

According to the theory, the atoms will form a geometry in such a way that there is minimum repulsion and maximum stability.  The carbon atoms are sp hybridized.

<u>So, it is of linear shape.</u>

3 0
3 years ago
Determine the volume of a piece of gold with a mass of 318.97g
djyliett [7]

Answer:

318 g / 19.32 g     v = 16. your volume is 16 hope this helps

Explanation:

6 0
3 years ago
At 1 atm, how much energy is required to heat 75.0 g H 2 O ( s ) at − 20.0 ∘ C to H 2 O ( g ) at 119.0 ∘ C?
Hitman42 [59]

Answer:

238,485 Joules

Explanation:

The amount of energy required is a summation of heat of fusion, capacity and vaporization.

Q = mLf + mC∆T + mLv = m(Lf + C∆T + Lv)

m (mass of water) = 75 g

Lf (specific latent heat of fusion of water) = 336 J/g

C (specific heat capacity of water) = 4.2 J/g°C

∆T = T2 - T1 = 119 - (-20) = 119+20 = 139°C

Lv (specific latent heat of vaporization of water) = 2,260 J/g

Q = 75(336 + 4.2×139 + 2260) = 75(336 + 583.8 + 2260) = 75(3179.8) = 238,485 J

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You use a nucleus with inflection on the arm processor.
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