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allochka39001 [22]
3 years ago
11

Suppose a 0.025M aqueous solution of sulfuric acid (H2SO4) is prepared. Calculate the equilibrium molarity of SO4−2. You'll find

information on the properties of sulfuric acid in the ALEKS Data resource. Round your answer to 2 significant digits.
Chemistry
1 answer:
FromTheMoon [43]3 years ago
4 0

<u>Answer:</u> The concentration of SO_4^{2-} at equilibrium is 0.00608 M

<u>Explanation:</u>

As, sulfuric acid is a strong acid. So, its first dissociation will easily be done as the first dissociation constant is higher than the second dissociation constant.

In the second dissociation, the ions will remain in equilibrium.

We are given:

Concentration of sulfuric acid = 0.025 M

Equation for the first dissociation of sulfuric acid:

       H_2SO_4(aq.)\rightarrow H^+(aq.)+HSO_4^-(aq.)

            0.025          0.025       0.025

Equation for the second dissociation of sulfuric acid:

                    HSO_4^-(aq.)\rightarrow H^+(aq.)+SO_4^{2-}(aq.)

<u>Initial:</u>            0.025            0.025      

<u>At eqllm:</u>      0.025-x          0.025+x        x

The expression of second equilibrium constant equation follows:

Ka_2=\frac{[H^+][SO_4^{2-}]}{[HSO_4^-]}

We know that:

Ka_2\text{ for }H_2SO_4=0.01

Putting values in above equation, we get:

0.01=\frac{(0.025+x)\times x}{(0.025-x)}\\\\x=-0.0411,0.00608

Neglecting the negative value of 'x', because concentration cannot be negative.

So, equilibrium concentration of sulfate ion = x = 0.00608 M

Hence, the concentration of SO_4^{2-} at equilibrium is 0.00608 M

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9.7 mm (9.7/1000 = 0.0097 m)

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By putting values,

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E = 19.89×10⁻²⁶ J.m / 9.7×10⁻³ m

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If 175mL of oxygen is produced at STP, how many grams of hydrogen peroxide, H2O2
Vlad [161]

Answer:

0.53g

Explanation:

We'll begin by converting 175mL to L. This is illustrated below:

1000mL = 1L

Therefore 175mL = 175/1000 = 0.175L

Next, we shall calculate the number of mole of O2 that occupy 0.175L. This is illustrated below:

1 mole of O2 occupy 22.4L at stp.

Therefore, Xmol of O2 will occupy 0.175L i.e

Xmol of O2 = 0.175/22.4

Xmol of O2 = 7.81×10¯³ mole

Therefore, 7.81×10¯³ mole of O2 occupy 175mL.

Next, we shall determine the number of mole of H2O2 that decomposed to produce 7.81×10¯³ mole of O2. This is illustrated below:

2H2O2 —> 2H2O + O2

From the balanced equation above,

2 moles of H2O2 decomposed to produce 1 mole of O2.

Therefore, Xmol of H2O2 will decompose to produce 7.81×10¯³ mole of O2 i.e

Xmol of H2O2 = 2 x 7.81×10¯³

Xmol of H2O2 = 1.562×10¯² mole

Therefore, 1.562×10¯² mole of H2O2 decomposed in the reaction.

Finally, we shall convert 1.562×10¯² mole of H2O2 to grams. This is illustrated below:

Molar mass of H2O2 = (2x1) + (16x2) = 34g/mol

Mole of H2O2 = 1.562×10¯² mole

Mass of H2O2 =..?

Mole = mass /Molar mass

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Cross multiply

Mass of H2O2 = 1.562×10¯² x 34

Mass of H2O2 = 0.53g

Therefore, 0.53g of Hydrogen peroxide, H2O2 were decomposition in the reaction.

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Answer:

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Molarity is the concentration that indicates moles of solute in 1 L of solution.

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Mass / Density = Volume

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