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marta [7]
4 years ago
5

Manufacturing traditional clayware ceramics typically involves driving off the water of hydration in the clay minerals. The rate

constant for the dehydration of kaolinite, a common clay mineral, is 1×10−4s−1 at 485 ∘c and 1×10−3s−1 at 525 ∘c. Calculate the activation energy for the dehydration of kaolinite.
Chemistry
1 answer:
zimovet [89]4 years ago
3 0

The relation between activation energy, rate constant and temperature is given by Arrhenius equation

Arrhenius equation is

ln (K2/ K1) = Ea / R (1/T1- 1/T2)

K2 =  1×10−3s−1  T2 =  525 ∘C = 798 K

K1 = 1×10−4s−1  T1 =  485 ∘c = 758 K

Ea = ?

R = gas constant = 8.314 J / mol K

ln (K2/ K1) = ln (10^-3 / 10^-4) = 2.303 = Ea /8 .314 (1/758 - 1 / 798)

2.303 = Ea / 8.314 (0.00132 - 0.00125)

Ea = 2.303 X 8.314 / (0.00132 - 0.00125)  = 273530.6 J / mole

Ea = activation energy = 273.531 kJ / mole

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Answer:

The type of salt to be added to the water is not known from the question but no worries, I will try to give you the step by step procedure to answer any type of question similar to this.

To answer this question, we should know some facts.

1. the molar freezing point depression constant of water (Kf) = 1.86 K kg/mol

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3. since the salt can dissociate if NaCl or KCl into two ions, the Van't Hoff factor ( i )= 2

Note that: the change in freezing point, molarity, deepression constant and van't Hoff factor are related by this formula;

                ΔTf = i Kf m

So lets take NaCl as the salt:

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1. calculate the number of moles

So we can calculate the molarity of the salt NaCl from the formula;

m = ΔTf / i Kf

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Next is to multiply the molarity by the mass of water. Density of water = 1kg/L

number of moles = 1.344 mol/kg * 1 Kg/L * 1 kg water

number of moles = 1.344 moles.

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4 years ago
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bixtya [17]

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Explanation:

Here are my notes on this section for anyone that needs them

Enthalpy and State Function

Bonds contain potential energy. Breaking and forming bonds involves energy. Reactants and products contain energy. Enthalpy (H) is a measure of heat and internal energy in a system.

A state function is a quantity whose change in magnitude during a process depends only on the beginning and end points the process, not the path taken between them. Enthalpy change during reaction depends only on the identity of reactants and products and their initial and finial condition

Enthalpy of Formation

enthalpy of formation (Hf) is the energy absorbed or released when a pure substance forms from elements in their standard states

Units: kJ/mol, kcal/mol

Standard state is the natural state of an element at 1 atm (atmosphere of pressure) and 25 degrees celsius. Hf for a pure element in its standard state is 0 kJ/mol.

H (hydrogen):    H2(g)

N (nitrogen): N2(g)

O (oxygen): O2(g)

F (fluorine): F2(g)

Cl (chlorine): Cl2(g)

Br (bromine): Br2(l)

Hg (mercury): Hg(l)

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Hrxn negative: exothermic reaction

Hrxn positive: endothermic reaction

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thermochemical equation: the chemical equation that shows the state of each substance involved and the energy change involved in a reaction

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