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mr_godi [17]
3 years ago
12

Determine the R/S orientation of the indicated chiral center(s) in the following molecules. If there is only one chiral center i

n the molecule, choose (none). Molecule #1 ( sobrerol ): Center a: _______ Center b: _______ Molecule #2 ( pulegone ): Center a: _______ Center b: _______
Chemistry
1 answer:
Nina [5.8K]3 years ago
4 0

Answer:

Molecule #1 ( sobrerol )

Center a: R

Center b: S

Molecule #2 ( pulegone )

Center a: none

Center b: R

Explanation:

The lowest priority group is curved the clockwise configuration of molecule is referred to as S and anti clockwise configuration is R. The absolute configuration of chiral center is defined by Cahn-ingold-Prelog rules. The sobrerol has center a as R configuration and center b as S configuration. The center a configuration of pulegone is none.

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A plot of binding energy per nucleon (Eb/ A) versus the mass number (A) shows that nuclei with a small mass number have a small
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a)   1.12 MeV / nucleon

b)   5.62 MeV / nucleon

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we can conclude that the binding energy has a maximum value for nuclei with a mass around 60

Explanation:

Binding energy = ( Δm * 931.5 ) MeV

Binding energy per nucleon = Binding energy in / Number of nucleon

<u>a) ²H = 1 neutron , 1 proton = 2 nucleons </u>

Given that the theoretical mass = 2.0141 u

Actual mass = 1.0078 u + 1.0087 u = 2.0165 u

Δm  = 2.0165 u - 2.0141 u = 2.4 * 10^-3 u

∴ Binding energy per nucleon = ( 2.4 * 10^-3  * 931.5 ) MeV / 2 nucleons

                                                  = 1.12 MeV / nucleon

<u>b) ⁷Li = 3 protons , 4 neutrons = 7 nucleons </u>

theoretical mass = 7.0160 u

Actual mass = ( 3 * 1.0078 ) + ( 4 * 1.0087 )  = 7.0582 u  

Δm  = ( 7.0582 u  - 7.0160 u  ) = 0.0422 u

∴ Binding energy per nucleon = ( 0.0422 * 931.5 ) / 7

                                                  = 5.62 MeV / nucleon

<u>C) ⁶²Ni = 28 protons , 34 neutrons = 62 nucleons </u>

Theoretical mass = 61.9283 u

Actual mass = ( 28 * 1.0078 ) u + ( 34 * 1.0087 ) u

                    = 62.5142 u

Δm = 0.5859 u  

∴ Binding energy per nucleon = ( 0.5859 * 931.5 ) / 62

                                                  = 8.80 MeV / nucleon

<u>D) ¹¹⁰Cd = 48 protons , 62 neutrons = 110 nucleons </u>

Theoretical mass = 109.9030 u

Actual mass = ( 48 * 1.0078 ) + ( 62 * 1.0087 )

                    = 110.9138 u

Δm  = ( 110.9138 - 109.9030 ) = 1.0108 u

∴ Binding energy per nucleon = ( 1.0108 * 931.5 ) / 110

                                                  = 8.56 MeV / nucleon

hence we can conclude that the binding energy has a maximum value for nuclei with a mass around 60

3 0
3 years ago
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