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topjm [15]
3 years ago
12

A hot-water stream at 70°C enters an adiabatic mixing chamber with a mass flow rate of 3.6 kg/s, where it is mixed with a stream

of cold water at 20°C. If the mixture leaves the chamber at 42°C, determine
(a) the mass flow rate of the cold water and
(b) the rate of entropy generation during this adiabatic mixing process. Assume all the streams are at a pressure of 200 kPa
Chemistry
1 answer:
cupoosta [38]3 years ago
5 0

Answer:

a) 4.58 kg/s

b) 0.105 kW/K

Explanation:

a) For the energy balance

qin = qout

min*cin*Tin = mout*cout*Tout

Where min is the mass flow that is entering the system, cin is the specific heat of the substance that is entering, Tin is the temperature of the substance that is entering, and the out is from the substances that are leaving the system. Because there is only water in the system cin = cout. The energy balance will be then:

mh*Th + mc*Tc = (mh + mc)*Tmix

Where h is from the hot water, c is from the cold water, and mix for the mixture that leaves the chamber. Th = 70ºC + 273 = 343 K, Tc = 20ºC + 273 = 293 K, Tmix = 42ºC + 273 = 315 K

3.6*343 + mc*293 = (3.6 + mc)*315

293mc - 315mc = 3.6*315 - 3.6*343

- mc*(315 - 293) = -3.6*(343 - 315)

mc = 3.6*(343 - 315)/(315 - 293)

mc = 3.6*28/22

mc = 4.58 kg/s

b) The entropy balance is:

Sin + Sout - Sgen = ΔSsystem

Where Sin is the entropy of the entering substances, Sout the entropy that the leaving substances, and Sgen the entropy that is generated in the process.

The entropy variantion for an adiabatic process is 0, so ΔSsystem = 0

Sgen = Sin + Sout

The sum of entropy is:

m*cp*ln(Tfinal/Tinitial), where cp is the specific heat (4.184 kJ/kg.K)

Sgen = mc*cp*ln(Tmix/Tc) + mh*cp*ln(Tmix/th)

Sgen = 4.58*4.184*ln(315/293) + 3.6*4.184*ln(315/343)

Sgen = 1.3874 + (-1.2827)

Sgen = 0.105 kW/K

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Steam initially at 0.3 MPa, 2500 C is cooled at constant volume. (a) At what temperature will steam become saturated vapour? [12
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Answer:

a. 123.9°C

b.

c.

Explanation:

Hello, I'm attaching a picture with the numerical development of this exercise.

a. Since the steam is overheated vapour, the specific volume is gotten from the corresponding table. Then, as it became a saturated vapour, we look for the interval in which the same volume of state 1 is, then we interpolate and get the temperature.

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5 0
3 years ago
A chemistry graduate student is given 125.mL of a 1.00M benzoic acid HC6H5CO2 solution. Benzoic acid is a weak acid with =Ka×6.3
lubasha [3.4K]

Answer:

53.9 g

Explanation:

When talking about buffers is very common the problem involves the use of the Henderson Hasselbach formula:

pH = pKa + log [A⁻]/[HA]

where  [A⁻] is the concentration of the conjugate base of the weak acid HA, and [HA] is the concentration of the weak acid.

We can calculate pKₐ from the given kₐ ( pKₐ = - log Kₐ ), and from there obtain the ratio  [A⁻]/HA].

Since we know the concentration of HC6H5CO2 and the volume of solution, the moles and mass of KC6H5CO2  can be determined.

So,

4.63 = - log ( 6.3 x 10⁻⁵ ) + log [A⁻]/[HA] = - (-4.20 ) + log [A⁻]/[HA]

⇒ log [A⁻]/[HA]  = 4.63 - 4.20 =  log [A⁻]/[HA]

0.43 = log [A⁻]/[HA]

taking antilogs to both sides of this equation:

10^0.43 =  [A⁻]/[HA] = 2.69

 [A⁻]/ 1.00 M = 2.69 ⇒ [A⁻] = 2.69 M

Molarity is moles per liter of solution, so we can calculate how many moles of  C6H5CO2⁻ the student needs to dissolve  in 125. mL ( 0.125 L ) of a 2.69 M solution:

( 2.69 mol C6H5CO2⁻ / 1L ) x 0.125 L  = 0.34 mol C6H5CO2⁻

The mass will be obtained by multiplying 0.34 mol times molecular weight for KC6H5CO2 ( 160.21 g/mol ):

0.34 mol x 160.21 g/mol = 53.9 g

3 0
3 years ago
Help would be majorly appreciated
Sophie [7]

Answer:

a) the atomic number is 15

b) the mass number is 15+16 = 31

c) element is phosphorus

d)Group 15 period 3

6 0
3 years ago
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