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bekas [8.4K]
3 years ago
9

What are the boiling points and freezing points (in oC) of a solution of 50.3 g of I2 in 350 g of chloroform? The kb = 3.63 oC/m

, the kf = 4.70 oC/m for CHCl3, and the molar mass of I2 is 253.8 g/mol. The normal boiling point for CHCl3 is 61.2 oC, and the normal freezing point for CHCl3 is -63.5 oC.
Chemistry
1 answer:
patriot [66]3 years ago
7 0

Answer:

Boiling point: 63.3°C

Freezing point: -66.2°C.

Explanation:

The boiling point of a solution increases regard to boiling point of the pure solvent. In the same way, freezing point decreases regard to pure solvent. The equations are:

<em>Boiling point increasing:</em>

ΔT = kb*m*i

<em>Freezing point depression:</em>

ΔT = kf*m*i

ΔT are the °C that change boiling or freezing point.

m is molality of the solution (moles / kg)

And i is Van't Hoff factor (1 for I₂ in chloroform)

Molality of 50.3g of I₂ in 350g of chloroform is:

50.3g * (1mol / 253.8g) = 0.198 moles in 350g = 0.350kg:

0.198 moles / 0.350kg = 0.566m

Replacing:

<em>Boiling point:</em>

ΔT = kb*m*i

ΔT = 3.63°C/m*0.566m*1

ΔT = 2.1°C

As boiling point of pure substance is 61.2°C, boiling point of the solution is:

61.2°C + 2.1°C = 63.3°C

<em>Freezing point:</em>

ΔT = kf*m*i

ΔT = 4.70°C/m*0.566m*1

ΔT = 2.7°C

As freezing point is -63.5°C, the freezing point of the solution is:

-63.5°C - 2.7°C = -66.2°C

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"46.7 g of water at 80.6 oC is added to a calorimeter that contains 45.33 g of water at 40.6 oC. If the final temperature of the
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<u>Answer:</u> The specific heat of calorimeter is 30.68 J/g°C

<u>Explanation:</u>

When hot water is added to the calorimeter, the amount of heat released by the hot water will be equal to the amount of heat absorbed by cold water and calorimeter.

Heat_{\text{absorbed}}=Heat_{\text{released}}

The equation used to calculate heat released or absorbed follows:

Q=m\times c\times \Delta T=m\times c\times (T_{final}-T_{initial})

m_1\times c_1\times (T_{final}-T_1)=-[(m_2\times c_2)+c_3](T_{final}-T_2)       ......(1)

where,

q = heat absorbed or released

m_1 = mass of hot water = 46.7 g

m_2 = mass of cold water = 45.33 g

T_{final} = final temperature = 59.4°C

T_1 = initial temperature of hot water = 80.6°C

T_2 = initial temperature of cold water = 40.6°C

c_1 = specific heat of hot water = 4.184 J/g°C

c_2 = specific heat of cold water = 4.184 J/g°C

c_3 = specific heat of calorimeter = ? J/g°C

Putting values in equation 1, we get:

46.7\times 4.184\times (59.4-80.6)=-[(45.33\times 4.184)+c_3](59.4-40.6)

c_3=30.68J/g^oC

Hence, the specific heat of calorimeter is 30.68 J/g°C

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