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Scilla [17]
3 years ago
7

50 mL of a mixture consisting of 0.019 M cerium (IV) and 2.7 M H2SO4, or sulfuric acid. Begin by preparing 100 mL of 2.7 M H2SO4

using the available solution of 42.3% w/w H2SO4. This concentration unit, which may be less familiar to you, is a weight-to-weight percent (100.0 g of the solution contains 42.3 g of H2SO4). The density of 42.3% w/w H2SO4 is 1.25 g solution/mL solution. Using a graduated cylinder, measure out the correct volume of 42.3% w/w H2SO4 and slowly add it to a 100-mL volumetric flask that already contains approximately 25 mL of deionized water.
Chemistry
1 answer:
yarga [219]3 years ago
8 0

Answer:

The correct volume of 42.3% w/w H₂SO₄ is 50,1 mL

Explanation:

In order to know the correct volume of 42.3% w/w H₂SO₄ needed, we need to know the <u>mass</u> of H₂SO₄ that is needed. We'll use the wanted concentration, the final volume and the molecular weight of sulphuric acid, thus:

2,7 M * 0,1 L * 98,079 g/mol = 26,48 g of sulphuric acid are needed.

Now we can calculate the correct volume, using the concentration of the available solution, and the density of said solution, thus:

26,48g H2SO4 *\frac{100g Solution}{42,3 g H2SO4}*\frac{1 mLsolution}{1,25gSolution}=50,08 mL

We would then need to measure 50,1 mL (rounded up) of 42.3% w/w H₂SO₄ with the graduated cylinder, and then add it to the volumetric flask.

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A mysterious white powder could be powdered sugar (C12H22O11), cocaine (C17H21NO4), codeine (C18H21NO3), norfenefrine (C8H11NO2)
rodikova [14]

Norfenefrine (C₈H₁₁NO₂).

<h3>Further explanation</h3>

We will solve a case related to one of the colligative properties, namely freezing point depression.

The freezing point of the solution is the temperature at which the solution begins to freeze. The difference between the freezing point of the solvent and the freezing point of the solution is called freezing point depression.

\boxed{ \ \Delta T_f = T_f(solvent) - T_f(solution) \ } \rightarrow \boxed{ \ \Delta T_f = K_f \times molality \ }

<u>Given:</u>

A mysterious white powder could be,

  • powdered sugar (C₁₂H₂₂O₁₁) with a molar mass of 342.30 g/moles,
  • cocaine (C₁₇H₂₁NO₄) with a molar mass of 303.35 g/moles,
  • codeine (C₁₈H₂₁NO₃) with a molar mass of 299.36 g/moles,
  • norfenefrine (C₈H₁₁NO₂) with a molar mass of 153.18 g/moles, or
  • fructose (C₆H₁₂O₆) with a molar mass of 180.16 g/moles.

When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

  • The solute = the powder
  • The solvent = ethanol
  • The freezing point of the solvent = −114.6°C
  • The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

  • Mass of solute = 82 mg = 0.082 g
  • Mass of solvent = density x volume, i.e., \boxed{ \ 0.789 \ \frac{g}{cm^3} \times 1.50 \ cm^3 = 1.1835 \ g = 0.00118 \ kg  \ }

We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

Now we combine it with the formula of freezing point depression.

\boxed{ \ \Delta T_f =  K_f \times \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }

\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }

\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }

We get \boxed{ \ Mr = 153.65 \ }

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>
  1. The molality and mole fraction of water brainly.com/question/10861444
  2. About the mass and density of ethylene glycol as an  antifreeze brainly.com/question/4053884
  3. About the solution as a homogeneous mixture  brainly.com/question/637791

Keywords: a mysterious white powder, sugar, cocaine, codeine, norfenefrine, fructose, the solute, the solvent, dissolved, ethanol, normal freezing point, the freezing point depression, the identity

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A student weighs out 0. 0422 g of magnesium metal. The magnesium metal is reacted with excess hydrochloric acid to produce hydro
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  • That is approximately 0.001758.
  • Furthermore, it claims that too much hydrochloric acid causes the metal magnesium to react, producing hydrogen gas.
  • The volume of collected gas is 43.9 cc, the mastic pressure is 22 cc, and a sample of hydrogen gas is collected over water in a meter.
<h3>Is it true that calculations made utilizing experimental and gathered data result in a percent error? </h3>
  • Consequently, we are aware that magnesium and chloride react.
  • We create 1 as the reaction ratio is 1:2.
  • The hydrogen and 1 are more.
  • Magnesium chloride is more.
  • Therefore, based on this equation, we can infer that the amount of hydrogen that would be created in this scenario is greater than the amount of magnesium present here, or 0.001758 more.
  • Among hydrogen, there is.
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  • Let's proceed with the calculations right now.
  • In this instance, you will discover that the solution is 9.077 times 10; that is all there is to it.

To learn more about Magnesium chloride reactions visit:

brainly.com/question/27891157

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Balance the Chemical Equations<br><br> MgF2 + Li2CO3---&gt; MgCO3 + LiF <br><br> Please Help
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Answer:

MgF2 + Li2CO3 ---> MgCO3 + 2LiF

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