Answer: 24.1 L
Explanation:
To calculate the final temperature of the system, we use the equation given by Charles' Law. This law states that volume of the gas is directly proportional to the temperature of the gas at constant pressure.
Mathematically,

where,
are the initial volume and temperature of the gas.
are the final volume and temperature of the gas.
We are given:

Putting values in above equation, we get:

Thus the volume of the sample when heated to 220.0oC and the pressure is constant is 24.1 L
Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is
and vapour pressure of component B is
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore, 
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.
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