A single replacement reaction, sometimes called a single displacement reaction, is a reaction in which one element is substituted for another element in a compound. The starting materials are always pure elements, such as a pure zinc metal or hydrogen gas, plus an aqueous compound.
Lithium i believe is the answer
First, we convert the given amount of energy into joules.
1 kJ = 1000 joules
2.2125 kJ = 2,212.5 Joules
Each kilocalorie contains 4,184 Joules
Kilocalories = 2,212.5 / 4,182
Kilocalories = 0.529
1 kilocalorie = 1000 calories
0.529 kilocalories = 529 calories
Boyle's law gives the relationship between pressure and volume of gas.
for a fixed amount of gas, at constant temperature the pressure of gas is inversely proportional to its volume.
PV = k
where P - pressure, V - volume and k - constant
P1V1 = P2V2
where parameters for the first instance are on the left side and parameters for the second instance are on the right side.
substituting the values in the equation
1.2 atm x 1.0 L = P x 4.0 L
P = 0.3 atm
new pressure is 0.3 atm