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Lynna [10]
3 years ago
14

Fe(II) can be precipitated from a slightly basic aqueous solution by bubbling oxygen through the solution, which converts Fe(II)

to insoluble Fe(III):
4Fe(OH)+(aq)+ 4OH-(aq)+O2(g)+2H2O(l) = 4Fe(OH)3(s)
how many grams of O2 are consumed to precipitate all of the iron in 85ml of 0.075 M Fe(II).
please explain step by step
Chemistry
1 answer:
vovangra [49]3 years ago
7 0

Answer:

0,051g of O₂

Explanation:

The reaction of precipitation of Fe is:

4Fe(OH)⁺(aq) + 4OH⁻(aq) + O₂(g) + 2H₂O(l) → 4Fe(OH)₃(s)

<em>-Where the Fe(OH)⁺ is Fe(II) and Fe(OH)₃ is Fe(III)-</em>

This reaction is showing you need 1 mol of O₂(g) per 4 moles of Fe(II) for a complete reaction.

85mL= 0,085L of 0,075M Fe(II) are:

0,085L*0,075M = 6,34x10⁻³ moles of Fe(II)

For a complete reaction of 6,34x10⁻³ moles of Fe(II) you need:

6,34x10⁻³ moles of Fe(II)×\frac{1molO_2}{4moles Fe(II)} =

1.59x10⁻³ moles of O₂. In grams:

1.59x10⁻³ moles of O₂×\frac{32g}{1molO_2} = <em>0,051g of O₂</em>

<em></em>

I hope it helps!

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vodka [1.7K]

Answer:

a. in pure water Solubility (x) = 1.26 x 10⁻⁴M

b. in 0.202M M⁺² Solubility (x) = 9.963 x 10⁻¹²M

The large drop in solubility is consistent with the common ion effect.

Explanation:

a. Solubility in pure water

Given:       M(OH)₂ ⇄ M⁺² + 2OH⁻

            I       ---            0          0

           C      ---             x          2x

           E       ---            x           2x

Ksp = [M⁺²][OH⁻]² = (x)(2x)² = 4x³ => x = CubeRt(Ksp/4)

solubility in pure water = x = CubeRt(8.05 x 10⁻¹²/4) = 1.26 x 10⁻⁴M

b. Solubility in presence of 0.202M M⁺² as common ion.

Given:       M(OH)₂ ⇄       M⁺²      +     2OH⁻

            I       ---            0.202M              0

           C      ---                 +x                 +2x

           E       ---           0.202M + x         2x

                                   ≈ 0.202M

Ksp = [M⁺²][2x]² = (0.202)(2x)² = (0.202)(4x²) = 8.05 x 10⁻¹²

=> x = (8.05 x 10⁻¹²)/(0.202)(4) = 9.963 x 10⁻¹²M

6 0
3 years ago
a solution of HCI contains 36 percent HCI,by mass and calculate the mole fraction of HCI in the solution?​
denis-greek [22]

Explanation:

You have a solution that contains 36 g HCl dissolved in 64 g water

Molar mass HCl = 36.45 g/mol

Mol HCl in 36 g = 36 g / 36.45 g/mol = 0.9876 mol

Molar mass H2O = 18 g/mol

Mol H2O in 64 g = 64 g / 18 g/mol = 3.5556 mol

Total mol = 0.9875 + 3.5556 = 4.5431 mol

Mol fraction HCl = 0.9876 mol / 4.5431 mol = 0.2174

Mol fraction H2O = 3.5556 / 4.5431 = 0.7826

The answer should have 2 significant digits:

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Mol fraction H2O = 0.78

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4 0
2 years ago
Which of these statements is not true about chemical reaction rates? a Temperature can change a reaction rate. b The amount of r
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The statement that is not true is: 'Temperature does not affect the reaction rate'.  

Explanation:

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Increasing the temperature increases the reaction rates because of the disproportionately large increase in the number of high energy collisions. It is only these collisions (possessing at least the activation energy for the reaction) which result in a reaction.

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A higher concentration of reactants leads to more effective collisions per unit time, which leads to an increased reaction rate.

c) Temperature can decrease the reaction rate. <u>This is true </u>

Decreasing the temperature decreases the reaction rates because of the  decrease in the number of high energy collisions. It will result in a slower reaction.

d) Temperature does not affect the reaction rate.  <u>This is not true. </u>

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