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Lynna [10]
3 years ago
14

Fe(II) can be precipitated from a slightly basic aqueous solution by bubbling oxygen through the solution, which converts Fe(II)

to insoluble Fe(III):
4Fe(OH)+(aq)+ 4OH-(aq)+O2(g)+2H2O(l) = 4Fe(OH)3(s)
how many grams of O2 are consumed to precipitate all of the iron in 85ml of 0.075 M Fe(II).
please explain step by step
Chemistry
1 answer:
vovangra [49]3 years ago
7 0

Answer:

0,051g of O₂

Explanation:

The reaction of precipitation of Fe is:

4Fe(OH)⁺(aq) + 4OH⁻(aq) + O₂(g) + 2H₂O(l) → 4Fe(OH)₃(s)

<em>-Where the Fe(OH)⁺ is Fe(II) and Fe(OH)₃ is Fe(III)-</em>

This reaction is showing you need 1 mol of O₂(g) per 4 moles of Fe(II) for a complete reaction.

85mL= 0,085L of 0,075M Fe(II) are:

0,085L*0,075M = 6,34x10⁻³ moles of Fe(II)

For a complete reaction of 6,34x10⁻³ moles of Fe(II) you need:

6,34x10⁻³ moles of Fe(II)×\frac{1molO_2}{4moles Fe(II)} =

1.59x10⁻³ moles of O₂. In grams:

1.59x10⁻³ moles of O₂×\frac{32g}{1molO_2} = <em>0,051g of O₂</em>

<em></em>

I hope it helps!

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The motion of the molecules decreases.

<u>Explanation</u>:

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5 0
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6 0
3 years ago
CH3COOH  CH3COO– + H+
Oxana [17]

(a)

pH = 4.77

; (b)

[

H

3

O

+

]

=

1.00

×

10

-4

l

mol/dm

3

; (c)

[

A

-

]

=

0.16 mol⋅dm

-3

Explanation:

(a) pH of aspirin solution

Let's write the chemical equation as

m

m

m

m

m

m

m

m

l

HA

m

+

m

H

2

O

⇌

H

3

O

+

m

+

m

l

A

-

I/mol⋅dm

-3

:

m

m

0.05

m

m

m

m

m

m

m

m

l

0

m

m

m

m

m

l

l

0

C/mol⋅dm

-3

:

m

m

l

-

x

m

m

m

m

m

m

m

m

+

x

m

l

m

m

m

l

+

x

E/mol⋅dm

-3

:

m

0.05 -

l

x

m

m

m

m

m

m

m

l

x

m

m

x

m

m

m

x

K

a

=

[

H

3

O

+

]

[

A

-

]

[

HA

]

=

x

2

0.05 -

l

x

=

3.27

×

10

-4

Check for negligibility

0.05

3.27

×

10

-4

=

153

<

400

∴

x

is not less than 5 % of the initial concentration of

[

HA

]

.

We cannot ignore it in comparison with 0.05, so we must solve a quadratic.

Then

x

2

0.05

−

x

=

3.27

×

10

-4

x

2

=

3.27

×

10

-4

(

0.05

−

x

)

=

1.635

×

10

-5

−

3.27

×

10

-4

x

x

2

+

3.27

×

10

-4

x

−

1.635

×

10

-5

=

0

x

=

1.68

×

10

-5

[

H

3

O

+

]

=

x

l

mol/L

=

1.68

×

10

-5

l

mol/L

pH

=

-log

[

H

3

O

+

]

=

-log

(

1.68

×

10

-5

)

=

4.77

(b)

[

H

3

O

+

]

at pH 4

[

H

3

O

+

]

=

10

-pH

l

mol/L

=

1.00

×

10

-4

l

mol/L

(c) Concentration of

A

-

in the buffer

We can now use the Henderson-Hasselbalch equation to calculate the

[

A

-

]

.

pH

=

p

K

a

+

log

(

[

A

-

]

[

HA

]

)

4.00

=

−

log

(

3.27

×

10

-4

)

+

log

(

[

A

-

]

0.05

)

=

3.49

+

log

(

[

A

-

]

0.05

)

log

(

[

A

-

]

0.05

)

=

4.00 - 3.49

=

0.51

[

A

-

]

0.05

=

10

0.51

=

3.24

[

A

-

]

=

0.05

×

3.24

=

0.16

The concentration of

A

-

in the buffer is 0.16 mol/L.

hope this helps :)

6 0
2 years ago
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slava [35]

Answer:

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Explanation:

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Where Ag⁺ is a silver cation and CH₃COO⁻ is the acetate anion (an organic anion). As we can see, from one single formula unit are obtained 2 ions (1 cation and 1 anion).

Therefore, the correct option is b) - 2

4 0
3 years ago
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