Answer:
Explanation:
Given parameters;
pH = 8.74
pH = 11.38
pH = 2.81
Unknown:
concentration of hydrogen ion and hydroxyl ion for each solution = ?
Solution
The pH of any solution is a convenient scale for measuring the hydrogen ion concentration of any solution.
It is graduated from 1 to 14
pH = -log[H₃O⁺]
pOH = -log[OH⁻]
pH + pOH = 14
Now let us solve;
pH = 8.74
since pH = -log[H₃O⁺]
8.74 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 1.82 x 10⁻⁹mol dm³
pH + pOH = 14
pOH = 14 - 8.74
pOH = 5.26
pOH = -log[OH⁻]
5.26 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] = 5.5 x 10⁻⁶mol dm³
2. pH = 11.38
since pH = -log[H₃O⁺]
11.38 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 4.17 x 10⁻¹² mol dm³
pH + pOH = 14
pOH = 14 - 11.38
pOH = 2.62
pOH = -log[OH⁻]
2.62 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] =2.4 x 10⁻³mol dm³
3. pH = 2.81
since pH = -log[H₃O⁺]
2.81 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 1.55 x 10⁻³ mol dm³
pH + pOH = 14
pOH = 14 - 2.81
pOH = 11.19
pOH = -log[OH⁻]
11.19 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] =6.46 x 10⁻¹²mol dm³
Answer:
EAST is the answer
Explanation:
For the moment, let us just think about one motion - - Earth's spin (or rotation) on its axis. Earth rotates or spins toward the east, and that's why the Sun, Moon, planets, and stars all rise in the east and make their way westward across the sky.
The reason why it is not considered this is because the material was made in a lab, not through nature, which is what is required to be considered as a true mineral.
Answer:
C.
will precipitate out first
the percentage of
remaining = 12.86%
Explanation:
Given that:
A solution contains:
![[Ca^{2+}] = 0.0440 \ M](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D%200.0440%20%5C%20M)
![[Ag^+] = 0.0940 \ M](https://tex.z-dn.net/?f=%5BAg%5E%2B%5D%20%3D%200.0940%20%5C%20M)
From the list of options , Let find the dissociation of 

where;
Solubility product constant Ksp of
is 
Thus;
![Ksp = [Ag^+]^3[PO_4^{3-}]](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BAg%5E%2B%5D%5E3%5BPO_4%5E%7B3-%7D%5D)
replacing the known values in order to determine the unknown ; we have :
![8.89 \times 10 ^{-17} = (0.0940)^3[PO_4^{3-}]](https://tex.z-dn.net/?f=8.89%20%5Ctimes%2010%20%5E%7B-17%7D%20%20%3D%20%280.0940%29%5E3%5BPO_4%5E%7B3-%7D%5D)
![\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3} = [PO_4^{3-}]](https://tex.z-dn.net/?f=%5Cdfrac%7B8.89%20%5Ctimes%2010%20%5E%7B-17%7D%7D%7B%280.0940%29%5E3%7D%20%20%3D%20%5BPO_4%5E%7B3-%7D%5D)
![[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D%5Cdfrac%7B8.89%20%5Ctimes%2010%20%5E%7B-17%7D%7D%7B%280.0940%29%5E3%7D)
![[PO_4^{3-}] =1.07 \times 10^{-13}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D1.07%20%5Ctimes%2010%5E%7B-13%7D)
The dissociation of 
The solubility product constant of
is 
The dissociation of
is :

Thus;
![Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![2.07 \times 10^{-33} = (0.0440)^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=2.07%20%5Ctimes%2010%5E%7B-33%7D%20%3D%20%280.0440%29%5E3%20%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}= [PO_4^{3-}]^2](https://tex.z-dn.net/?f=%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%280.0440%29%5E3%7D%3D%20%20%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%5E2%20%3D%20%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%280.0440%29%5E3%7D)
![[PO_4^{3-}]^2 = 2.43 \times 10^{-29}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%5E2%20%3D%202.43%20%5Ctimes%2010%5E%7B-29%7D)
![[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D%20%5Csqrt%7B2.43%20%5Ctimes%2010%5E%7B-29%7D)
![[PO_4^{3-}] =4.93 \times 10^{-15}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D4.93%20%5Ctimes%2010%5E%7B-15%7D)
Thus; the phosphate anion needed for precipitation is smaller i.e
in
than in

Therefore:
will precipitate out first
To determine the concentration of
when the second cation starts to precipitate ; we have :
![Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![2.07 \times 10^{-33} = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2](https://tex.z-dn.net/?f=2.07%20%5Ctimes%2010%5E%7B-33%7D%20%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%281.07%20%5Ctimes%2010%5E%7B-13%7D%29%5E2)
![[Ca^{2+}]^3 = \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%5E3%20%3D%20%20%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%281.07%20%5Ctimes%2010%5E%7B-13%7D%29%5E2%7D)
![[Ca^{2+}]^3 =1.808 \times 10^{-7}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%5E3%20%3D1.808%20%5Ctimes%2010%5E%7B-7%7D)
![[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D%5Csqrt%5B3%5D%7B1.808%20%5Ctimes%2010%5E%7B-7%7D%7D)
![[Ca^{2+}] =0.00566](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D0.00566)
This implies that when the second cation starts to precipitate ; the concentration of
in the solution is 0.00566
Therefore;
the percentage of
remaining = concentration remaining/initial concentration × 100%
the percentage of
remaining = 0.00566/0.0440 × 100%
the percentage of
remaining = 0.1286 × 100%
the percentage of
remaining = 12.86%