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hodyreva [135]
3 years ago
7

The rate constant for this first‑order reaction is 0.550 s−10.550 s−1 at 400 ∘C.400 ∘C. A⟶products A⟶products How long, in secon

ds, would it take for the concentration of AA to decrease from 0.690 M0.690 M to 0.220 M?
Chemistry
1 answer:
Alisiya [41]3 years ago
5 0

Answer:

t=2.08s

Explanation:

Hello,

In this case, for first order reactions, we can use the following integrated rate law:

ln(\frac{[A]}{[A]_0} )=kt

Thus, we compute the time as shown below:

t=-\frac{ln(\frac{[A]}{[A]_0} )}{k}=- \frac{ln(\frac{0.220M}{0.690M} )}{0.55s^{-1}} \\\\t=-\frac{-1.14}{0.550s^{-1}}\\ \\t=2.08s

Best regards.

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Determine the pHpH of an HFHF solution of each of the following concentrations. In which cases can you not make the simplifying
PIT_PIT [208]

The question is incomplete, complete question is :

Determine the pH of an HF solution of each of the following concentrations. In which cases can you not make the simplifying assumption that x is small? (K_a for HF is 6.8\times 10^{-4}.)

[HF] = 0.280 M

Express your answer to two decimal places.

Answer:

The pH of an 0.280 M HF solution is 1.87.

Explanation:3

Initial concentration if HF = c = 0.280 M

Dissociation constant of the HF = K_a=6.8\times 10^{-4}

HF\rightleftharpoons H^++F^-

Initially

c          0            0

At equilibrium :

(c-x)      x             x

The expression of disassociation constant is given as:

K_a=\frac{[H^+][F^-]}{[HF]}

K_a=\frac{x\times x}{(c-x)}

6.8\times 10^{-4}=\frac{x^2}{(0.280 M-x)}

Solving for x, we get:

x = 0.01346 M

So, the concentration of hydrogen ion at equilibrium is :

[H^+]=x=0.01346 M

The pH of the solution is ;

pH=-\log[H^+]=-\log[0.01346 M]=1.87

The pH of an 0.280 M HF solution is 1.87.

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