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gogolik [260]
2 years ago
6

You need to produce a buffer solution that has a pH of 5.31. You already have a solution that contains 10. mmol (millimoles) of

acetic acid. How many millimoles of acetate (the conjugate base of acetic acid) will you need to add to this solution? The pKa of acetic acid is 4.74.
Chemistry
1 answer:
Karolina [17]2 years ago
3 0

Answer:

37 mmol of acetate need to add to this solution.

Explanation:

Acetic acid is an weak acid. According to Henderson-Hasselbalch equation for a buffer consist of weak acid (acetic acid) and its conjugate base (acetate)-

pH=pK_{a}(acetic acid)+log[\frac{mmol of CH_{3}COO^{-}}{mmol of CH_{3}COOH }]

Here pH is 5.31, pK_{a} (acetic acid) is 4.74 and number of mmol of acetic acid is 10 mmol.

Plug in all the values in the above equation:

5.31=4.74+log[\frac{mmol of CH_{3}COO^{-}}{10}]

or, mmol of CH_{3}COO^{-} = 37

So 37 mmol of acetate need to add to this solution.

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a student needs to use 0.575 moles of sodium chloride in an experiment. How many grams should he mass out?
Bad White [126]

The molecular weight of NaCl is 58.44 g/mol.  

0.575 mol * 58.44 g/mol = 33.6 grams of NaCl

5 0
3 years ago
If a 95.27 mL sample of acetic acid (HC2H3O2) is titrated to the equivalence point with 79.06 mL of 0.113 M KOH, what is the pH
KATRIN_1 [288]

Answer:

8.73

Explanation:

The concentration of acetic acid can be determined as follows:

M_1V_1 = M_2V_2\\(KOH) = (CH_3COOH)

M_{KOH}=0.113 M\\V_{KOH}=79.06 mL

V_{CH_3COOH}=95.27 \\\\M_{CH_3COOH)=?????

M_{CH3COOH} = \frac{M_{KOH}*V_{KOH}}{V_{CH_3COOH}}

M_{CH3COOH} = \frac{0.113*79.06}{95.27}

M_{CH3COOH} = 0.094 M

Moles of CH_3COOH = 95.27* 10^{-3}* 0.094

=0.0090 moles

Moles of  KOH = 79.06*10^{-3}*0.113

= 0.0090 moles

The equation for the reaction can be expressed as :

CH_3COOH     +      KOH     ----->      CH_3COO^{-}K^+      +     H_2O

Concentration of CH_3COO^{- ion = \frac{0.0090}{Total volume (L)}

= \frac{0.0090}{(95.27+79.06)} *1000

= 0.052 M

Hydrolysis of  CH_3COO^{- ion:

CH_3COO^{-      +       H_2O      ----->      CH_3COOH       +     OH^-

K = \frac{K_w}{K_a} = \frac{x*x}{0.052-x}

⇒    \frac{10^{-14}}{1.82*10^{-5}}= \frac{x*x}{0.052-x}

=     0.5494*10^{-9}= \frac{x*x}{0.052-x}

As K is so less, then x appears to be a very infinitesimal small number

0.052-x ≅ x

0.5494*10^{-9}= \frac{x^2}{0.052}

x^2 = 0.5494*10^{-9}*0.052

x^2 = 0.286*10^{-10

x = \sqrt{0.286*10^{-10

x =0.535*10^{-5}M

[OH] = x =0.535*10^{-5}

pOH = -log[OH^-]

pOH = -log[0.535*10^{-5}]

pOH = 5.27

pH = 14 - pOH

pH = 14 - 5.27

pH = 8.73

Hence, the pH of the titration mixture = 8.73

8 0
3 years ago
The constant volume heat capacity of a gas can be measured by observing the decrease in temperature when it expands adiabaticall
miv72 [106K]

Answer:

The value is  C_p  = 42. 8 J/K\cdot mol

Explanation:

From the question we are told that  

     \gamma = \frac{C_p }{C_v}

The  initial volume of the  fluorocarbon gas is  V_1 = V

 The final  volume of the fluorocarbon gas isV_2 = 2V

  The initial  temperature of the fluorocarbon gas is  T_1  =  298.15 K

  The final  temperature of the fluorocarbon gas is T_2  =  248.44 K

   The initial  pressure is P_1  = 202.94\  kPa

    The final   pressure is  P_2  =  81.840\  kPa

Generally the equation for  adiabatically reversible expansion is mathematically represented as

       T_2 =  T_1  * [ \frac{V_1}{V_2} ]^{\frac{R}{C_v} }

Here R is the ideal gas constant with the value  

        R =  8.314\  J/K \cdot mol

So  

   248.44 =   298.15  * [ \frac{V}{2V} ]^{\frac{8.314}{C_v} }

=> C_v  =  31.54 J/K\cdot mol

Generally adiabatic reversible expansion can also be mathematically expressed as

    P_2 V_2^{\gamma} = P_1 V_1^{\gamma}

=>[ 81.840 *10^3] [2V]^{\gamma} = [202.94 *10^3] V^{\gamma}    

=>  2^{\gamma} =  2.56

=>    \gamma =  1.356

So

     \gamma  =  \frac{C_p}{C_v} \equiv  1.356 = \frac{C_p}{31.54}

=>    C_p  = 42. 8 J/K\cdot mol

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