Answer:
(a) Increases
(b) Increases
(c) Increases
(d) Increases
(e) Decreases
Explanation:
The tensile modulus of a semi-crystalline polymer depends on the given factors as:
(a) Molecular Weight:
It increases with the increase in the molecular weight of the polymer.
(b) Degree of crystallinity:
Tensile strength of the semi-crystalline polymer increases with the increase in the degree of crystallinity of the polymer.
(c) Deformation by drawing:
The deformation by drawing in the polymer results in the finely oriented chain structure of the polymer with the greater inter chain secondary bonding structure resulting in the increase in the tensile strength of the polymer.
(d) Annealing of an undeformed material:
This also results in an increase in the tensile strength of the material.
(e) Annealing of a drawn material:
A semi crystalline material which is drawn when annealed results in the decreased tensile strength of the material.
Answer: hello attached below is the properly written chain reaction to your question
answer :
d[NO] / dt = ![k_{1f} [O] [N_{2}] + K_{2f} [N][O_{2} ] + K_{3f}[N][OH]](https://tex.z-dn.net/?f=k_%7B1f%7D%20%5BO%5D%20%5BN_%7B2%7D%5D%20%2B%20K_%7B2f%7D%20%20%5BN%5D%5BO_%7B2%7D%20%5D%20%2B%20K_%7B3f%7D%5BN%5D%5BOH%5D)
d[N] / dt = ![k_{1f} [O] [N_{2}] + K_{2f} [N][O_{2} ] - K_{3f}[N][OH]](https://tex.z-dn.net/?f=k_%7B1f%7D%20%5BO%5D%20%5BN_%7B2%7D%5D%20%2B%20K_%7B2f%7D%20%20%5BN%5D%5BO_%7B2%7D%20%5D%20-%20K_%7B3f%7D%5BN%5D%5BOH%5D)
Explanation:
<u>write out expressions for d[NO] / dt and d[N] / dt</u>
Given :
properly written chain reaction ( attached below)
Expression for d[NO] / dt can be written as
![k_{1f} [O] [N_{2}] + K_{2f} [N][O_{2} ] + K_{3f}[N][OH]](https://tex.z-dn.net/?f=k_%7B1f%7D%20%5BO%5D%20%5BN_%7B2%7D%5D%20%2B%20K_%7B2f%7D%20%20%5BN%5D%5BO_%7B2%7D%20%5D%20%2B%20K_%7B3f%7D%5BN%5D%5BOH%5D)
Expression for d[N] / dt can be written as
![k_{1f} [O] [N_{2}] + K_{2f} [N][O_{2} ] - K_{3f}[N][OH]](https://tex.z-dn.net/?f=k_%7B1f%7D%20%5BO%5D%20%5BN_%7B2%7D%5D%20%2B%20K_%7B2f%7D%20%20%5BN%5D%5BO_%7B2%7D%20%5D%20-%20K_%7B3f%7D%5BN%5D%5BOH%5D)
Explanation:
Pressure = force/area
Pressure stays the same.
If the area is doubled the force is doubled.