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eimsori [14]
3 years ago
15

if a sample of gas at 25.2 c has a volume of 536mL at 637 torr, what will its volume be if the pressure is increased to 712 torr

?
Chemistry
1 answer:
nignag [31]3 years ago
6 0
Considering ideal gas:
PV= RTn

T= 25.2°C = 298.2 K

P1= 637 torr = 0.8382 atm

V1= 536 mL = 0.536 L

:. R=0.082 atm.L/K.mol

:. n= (P1V1)/(RT) = ((0.8382 atm) x (0.536 L))/
((0.082 atmL/Kmol) x (298.2K))

:. n= O.0184 mol

Then,
P2= 712 torr = 0.936842 atm

V2 = RTn/P2 = [(0.082atmL/
Kmol) x (298.2K) x (0.0184mol) ]/(0.936842atm)

:.V2 = 0.4796 L
OR
V2 = 479.6 ml

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The given balanced equilibrium reaction is,

                            cyclohexane  ⇔  methylcyclopentane

Initial conc.                 0.025 M           0

At eqm. conc.       (0.025-x)M       (x) M

The expression for equilibrium constant for this reaction will be,

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Now put all the given values in this expression, we get :

0.12=\frac{(x)}{(0.025-x)}

By solving the term 'x', we get :

x =  0.0027

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Concentration of methylcyclopentane at equilibrium = (x ) M = (0.0027) M

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