In buffer solution there is an equilibrium between the acid HA and its conjugate base A⁻: HA(aq) ⇌ H⁺(aq) + A⁻(aq).
When acid (H⁺ ions) is added to the buffer solution, the equilibrium is shifted to the left, because conjugate base (A⁻) reacts with hydrogen cations from added acid, according to Le Chatelier's principle: H⁺(aq) + A⁻(aq) ⇄ HA(aq). So, the conjugate base (A⁻) consumes some hydrogen cations and pH is not decreasing (less H⁺ ions, higher pH of solution).
A buffer can be defined as a substance that prevents the pH of a solution from changing by either releasing or absorbing H⁺ in a solution.
Buffer is a solution that can resist pH change upon the addition of an acidic or basic components and it is able to neutralize small amounts of added acid or base, pH of the solution is relatively stable
<span>Among the given choices, the third option is the only one which illustrates single replacement.
(3)H2SO4 + Mg --> H2 + MgSO4
A single replacement is also termed as single-displacement reaction, a reaction by which an element in a compound, displaces another element.
It can be illustrated this way:
X + Y-Z → X-Z + Y</span>
Molarity is a concentration unit, defined to be the number of moles of solute divided by the number of liters of solution.
To solve this problem, we use Beer's Law: A= ε.l.c
A is the absorbance- 0,558
<span>ε is</span> the molar absorptivity- is <span>15000 </span><span><span>L⋅mol-1</span><span>cm-1</span></span>
<span>l is </span>the length of the cuvette- 1 cm
<span>c is</span> the molar concentration
Applying the formula,
0,558= 15000 x 1 x c
0,558/15000= c
c= <span>3.72×<span>10⁻⁵ </span> <span>mol⋅L<span>⁻¹</span></span></span>
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a metal with a large number of free-flowing electrons most likely have good conductivity