1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
zheka24 [161]
2 years ago
11

A concentrated binary solution containing mostly species 2 (but x2 ≠ 1) is in equilib- rium with a vapor phase containing both s

pecies 1 and 2. The pressure of this two- phase system is 1 bar; the temperature is 25°C. At this temperature, 1 = 200 bar and P2sat = 0.10 bar. Determine good estimates of x1 and y1. State and justify all assumptions.
Chemistry
2 answers:
Murljashka [212]2 years ago
5 0

Answer:X= 4.5x 10^-3 ; Y= 0.9  

Explanation:

Here, a binary solution which contains 2 species is in equilibrium with a vapor phase containing two species, 1 and 2

Given that the pressure of this 2 phase system is =1 bar

We will use the following assumptions to solve this problem

1. The vapor phase is ideal at a pressure

2.   that Henry’s law applies to dilute solutions

3. that Raoult law applies to concentrated solutions

from the question we have that  

Henry’s constant of species 1 , H1 =200bar,  

Saturated vapor phase of species 2, = 0.10 bar

Temp of system= 25°C = 298k

Let us apply henry’s law for specires 1

y1P= H1X1-------eqn 1

where y_1= mole fraction of species 1 in vapor phase

p=total pressure of system

x1=mole fraction of species 2 in liquid phase

Also applying Raoult's law for species 2

Y2P= 2 X2------Eqn 2

Combining  Eqn 1 and  2

P=H1X1 + ^p^{sat}2 X2  

Then  Substituting The given variables  ie  200bar=H1, 0.10bar=2= in eqn 3 to solve for x

P=H1X1+(1+ X1)P2sat

1 bar= 200bar X x1+ (1-x)0.10bar

X=4.5X10-3

=mole fraction of species in  Liquid phase=4.5 x 10^-3

Substituting for xi=4.5x 10^-3 in eqn n1 becomes  

Y1P= H1X1-------eqn 1

y1 x 1 bar= 200bar x 4.5x 10^-3

y1=0.9

mole fraction of species  in vapour phase=0.9

marusya05 [52]2 years ago
4 0

Answer:

x1= 4.5 × 10^-3, y1= 0.9

Explanation:

A binary solution having two species is in equilibrium in a vapor phase comprising of species 1 and 2

Take the basis as the pressure of the 2 phase system is 1 bar. The assumption are as follows:

1. The vapor phase is ideal at pressure of 1 bar

2. Henry's law apply to dilute solution only.

3. Raoult's law apply to concentrated solution only.

Where,

Henry's constant for species 1 H= 200bar

Saturation vapor pressure of species 2, P2sat= 0.10bar

Temperature = 25°C= 298.15k

Apply Henry's law for species 1

y1P= H1x1...... equation 1

y1= mole fraction of species 1 in vapor phase.

P= Total pressure of the system

x1= mole fraction of species 1 in liquid phase.

Apply Raoult's law for species 2

y2P= P2satx2...... equation 2

From the 2 equations above

P=H1x1 + P2satx2

200bar= H1

0.10= P2sat

1 bar= P

Hence,

P=H1x1 + (1 - x1) P2sat

1bar= 200bar × x1 + (1 - x1) 0.10bar

x1= 4.5 × 10^-3

The mole fraction of species 1 in liquid phase is 4.5 × 10^-3

To get y, substitute x1=4.5 × 10^-3 in equation 1

y × 1 bar = 200bar × 4.5 × 10^-3

y1= 0.9

The mole fraction of species 1 in vapor phase is 0.9

You might be interested in
Which of the following compounds' solubility will not be affected by a low pH in solution?
Whitepunk [10]

The compound solubility which will not be affected by a low pH in solution is AgBr.

<h3>What is pH?</h3>

pH is a measure of the acidity or basicity of any solution and according to the pH scale 0 to 6.9 shows the acidity, 7 is neutral and 7.1 to 14 shows the basicity of any solution.

  • AgBr is sparingly soluble in water and not soluble in acids, so if we low the pH of the solution towards the acidity its solubility not affected.
  • NiCO₃ is a basic salt and and shows solubility in the acidic medium so change in pH will affect its solubility.
  • Co(OH)₂ it is also a basic compound and shows its solubility in the acidic medium and get affected when change in pH takes place.
  • PbF₂ is a strong base and also shows solubility in the acidic medium easily, so get affected when change in pH takes place.
  • In CuS, sulphide is basic ion and whole compound shows solubility in the acidic medium and get affected when low pH of solution takes place.

AgBr is not affected by a low pH in solution.

To know more about solubility, visit the below link:

brainly.com/question/23946616

3 0
2 years ago
Read 2 more answers
Classify the following reaction.
Klio2033 [76]

Answer:

Explanation:

combustion  reacts with oxygen

7 0
3 years ago
Need chem help asap
gavmur [86]

Oh I’m so4+ds2=563

Which is the answer

5 0
3 years ago
The smallest particle of an element is a(n) .<br>atom<br>molecule<br>DNA​
mamaluj [8]

Answer:

An atom is the smallest particle of an element

5 0
2 years ago
Balanced equation for solid magnesium oxide
Y_Kistochka [10]

Answer:

Mg + O2 → MgO

Explanation:

3 0
3 years ago
Other questions:
  • In the field of chemistry, standard temperature and pressure conditions are:
    11·2 answers
  • How many grams are in 2.40 moles of sodium hydroxide (NaOH)?
    12·1 answer
  • Calculate the concentration (m) of sodium ions in a solution made by diluting 80.0 ml of a 0.174 m solution of sodium sulfide to
    15·1 answer
  • What is the difference between a compound and a mixture? Group of answer choices One is a solid and the other is a liquid. They
    10·1 answer
  • Which statement best compares and contrasts lipids and carbohydrates?
    5·2 answers
  • This is when water freezes, expands, pushing the rock apart slowly over a period<br> of time.
    10·1 answer
  • Read the sentence from the introduction [paragraphs 1-3].
    9·1 answer
  • The following quantities were reported on the labels of commercial products. Determine the number of significant figures in each
    6·1 answer
  • A gas has a volume of 62.65L at O degrees Celsius and 1 atm. At what temperature in Celsius would the volume of the gas be 78.31
    6·1 answer
  • In this equation, what should be the coefficients of the reactants and products?
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!