Answer:
a) ΔGº= -49,9 KJ/mol = - 50 KJ/mol
b) The reaction goes to the right to formation of products
c) ΔG= 84,42 KJ/mol. The direction is to reactive, to the left
Explanation:
a) ΔGº= - RTLnKf
You need to convert Cº to K. 25ºC=298K
Then, ΔGº= - 3,814 J/molK * 298K* Ln(5.6 *10^8)= - 49906 J/mol = -49,9 KJ/mol = - 50 KJ/mol
b) The ΔGº < 0, that means the direct reaction is spontaneous when te reactive and products are in standard state. In other words the reaction goes to the right, to formation of products
c) The general ecuation for chemical reaction is aA + bB → cD + dD. Thus
ΔG=ΔGº + RTLn (([C]^c*[D]^d)/[A]^a*[B]^b)
In this case,
ΔG=ΔGº + RTLn ([Ni(NH3)62+] / [Ni2+]*[NH3]^6 )= 84417 J/mol =84,42 KJ/mol
ΔG >0 means the reaction isn't spontaneous in the direction of the products. Therefore the direction is to reactive, to the left
Answer:
Postassium bisulphate - KHSO4 - can be used as an food preservative to protect the food from micro-organisms.
Answer:
N₂ = 0.7515atm
O₂ = 0.1715atm
NO = 0.0770atm
Explanation:
For the reaction:
N₂(g) + O₂(g) ⇄ 2NO(g)
Where Kp is defined as:
Pressures in equilibrium are:
N₂ = 0.790atm - X
O₂ = 0.210atm - X
NO = 2X
Replacing in Kp:
0.0460 = [2X]² / [0.790atm - X] [0.210atm - X]
0.0460 = 4X² / 0.1659 - X + X²
0.0460X² - 0.0460X + 7.6314x10⁻³ = 4X²
-3.954X² - 0.0460X + 7.6314x10⁻³ = 0
Solving for X:
X = - 0.050 → False answer. There is no negative concentrations.
X = <em>0.0385 atm</em> → Right answer.
Replacing for pressures in equilibrium:
N₂ = 0.790atm - X = <em>0.7515atm</em>
O₂ = 0.210atm - X = <em>0.1715atm</em>
NO = 2X = <em>0.0770atm</em>
Answer:
I don't know what to say . just for points
