<span> The </span>formula mass<span> is calculated by adding up all the atomic </span>masses <span>for every atom in the </span>formula<span>. First, we need to know the atomic masses of the atoms involved.
H = 1.01 amu
S = 32.06 amu
Formula mass = 2 x </span>1.01 amu + 2 x 32.06 amu = 66.14 formula mass unit
½H2(g) + ½I2(g) → HI(g) ΔH = +6.2 kcal/mol
or...
½H2(g) + ½I2(g) + 6,2kcal/mole → HI(g)
________
21.0 kcal/mole + C(s) + 2S(s) → CS2(l)
or...
C(s) + 2S(s) → CS2(l) ΔH = +2,1 kcal/mole
_________
ΔH > 0 ----------->>> ENDOTHERMIC REACTIONS
To calculate the <span>δ h, we must balance first the reaction:
NO + 0.5O2 -----> NO2
Then we write all the reactions,
2O3 -----> 3O2 </span><span>δ h = -426 kj eq. (1)
O2 -----> 2O </span><span>δ h = 490 kj eq. (2)
NO + O3 -----> NO2 + O2 </span><span>δ h = -200 kj eq. (3)
We divide eq. (1) by 2, we get
</span>O3 -----> 1.5O2 δ h = -213 kj eq. (4)
Then, we subtract eq. (3) by eq. (4)
NO + O3 -----> NO2 + O2 δ h = -200 kj
- (O3 -----> 1.5 O2 δ h = -213 kj)
NO -----> NO2 - 0.5O2 δ h = 13 kj eq. (5)
eq. (2) divided by -2. (Note: Dividing or multiplying by negative number reverses the reaction)
O -----> 0.5O2 <span>δ h = -245 kj eq. (6)
</span>
Add eq. (6) to eq. (5), we get
NO -----> NO2 - 0.5O2 δ h = 13 kj
+ O -----> 0.5O2 δ h = -245 kj
NO + O ----> NO2 δ h = -232 kj
<em>ANSWER:</em> <em>NO + O ----> NO2 δ h = -232 kj</em>
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