Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
the formula for tht is C8H8O4
no. of moles=mass/molar mass
=97.3/18
=<u>5.40555555556 moles</u>
<span>J.j thomson a british physicist was the first to identify the electron in 1987</span>
Answer : The rate law for the overall reaction is, ![Rate=k[NO]^2[H_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BNO%5D%5E2%5BH_2%5D)
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
As we are given the mechanism for the reaction :
Step 1 :
(slow)
Step 2 :
(fast)
Overall reaction : 
The rate law expression for overall reaction should be in terms of
.
As we know that the slow step is the rate determining step. So,
The slow step reaction is,

The expression of rate law for this reaction will be,
![Rate=k[NO]^2[H_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BNO%5D%5E2%5BH_2%5D)
Hence, the rate law for the overall reaction is, ![Rate=k[NO]^2[H_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BNO%5D%5E2%5BH_2%5D)