Answer:
8.3 kJ
Explanation:
In this problem we have to consider that both water and the calorimeter absorb the heat of combustion, so we will calculate them:
q for water:
q H₂O = m x c x ΔT where m: mass of water = 944 mL x 1 g/mL = 944 g
c: specific heat of water = 4.186 J/gºC
ΔT : change in temperature = 2.06 ºC
so solving for q :
q H₂O = 944 g x 4.186 J/gºC x 2.06 ºC = 8,140 J
For calorimeter
q calorimeter = C x ΔT where C: heat capacity of calorimeter = 69.6 ºC
ΔT : change in temperature = 2.06 ºC
q calorimeter = 69.60J x 2.06 ºC = 143.4 J
Total heat released = 8,140 J + 143.4 J = 8,2836 J
Converting into kilojoules by dividing by 1000 we will have answered the question:
8,2836 J x 1 kJ/J = 8.3 kJ
Answer:
56.9 mmoles of acetate are required in this buffer
Explanation:
To solve this, we can think in the Henderson Hasselbach equation:
pH = pKa + log ([CH₃COO⁻] / [CH₃COOH])
To make the buffer we know:
CH₃COOH + H₂O ⇄ CH₃COO⁻ + H₃O⁺ Ka
We know that Ka from acetic acid is: 1.8×10⁻⁵
pKa = - log Ka
pKa = 4.74
We replace data:
5.5 = 4.74 + log ([acetate] / 10 mmol)
5.5 - 4.74 = log ([acetate] / 10 mmol)
0.755 = log ([acetate] / 10 mmol)
10⁰'⁷⁵⁵ = ([acetate] / 10 mmol)
5.69 = ([acetate] / 10 mmol)
5.69 . 10 = [acetate] → 56.9 mmoles
The periodic table of the elements are describe the electronic configuration of the elements on which the properties of the elements depends. Among the given groups only metal, non-metal and semi-metal group are the part of periodic table. The metallic property depends upon the binding energy of the electrons with the nucleus. Thus the elements which have the valence electrons more near to the nucleus that is s-block elements are more metallic in nature. On the other hand the elements which have the valence electrons far from the nucleus are more non-metallic in nature like p-block elements. However the binding energy or the attraction of the outermost electrons to the nucleus depends not only its valence electrons position but also some other factors like shielding effect, effective nuclear charge etc.
The elements which are in between the metals and non-metals can be classified as semi-metals.
Although the conductivity of a material is an inherent property of the metals but sometime the nonmetals or semi-metals are also behave like a conductor due to presence of the other elements, thus it cannot be a p[property of the periodic table. Similarly acidity, flammable gases are not part of the periodic table.
Physical changes are changes affecting the form of a chemical substance, but not its chemical composition. Physical changes are used to separate mixtures into their component compounds, but can not usually be used to separate compounds into chemical elements or simpler compounds.
Ex: cutting a paper, gaining weight, cutting hair
