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Harrizon [31]
3 years ago
8

A chemist must prepare of 800.0 ml potassium hydroxide solution with a pH of 13.00 at 25°.

Chemistry
1 answer:
ArbitrLikvidat [17]3 years ago
4 0

Answer:

4.48 grams is the mass of potassium hydroxide that the chemist must weigh out in the second step.

Explanation:

The pH of the solution = 13.00

pH + pOH = 14

pOH = 14 - pH = 14 - 13.00 = 1.00

pOH=-\log[OH^-]

1.00=-\log[OH^-]

[OH^-]=10^{-1.00} M=0.100 M

KOH(aq)\rightarrow K^+(aq)+OH^-(aq)

[KOH]=[OH^-]=[K^+]=0.100 M

Molariy of the KOH = 0.100 M

Volume of the KOH solution = 800 mL= 0.800 L

1 mL = 0.001 L

Moles of KOH = n

Molarity=\frac{Moles}{Volume(L)}

0.100 M=\frac{n}{0.800 L}

n = 0.0800 mol

Mass of 0.0800 moles of KOH :

0.0800 mol × 56 g/mol = 4.48 g

4.48 grams is the mass of potassium hydroxide that the chemist must weigh out in the second step.

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<em>Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical</em>

<em />

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

  • <em>pKa NH₃/NH₄⁺</em>

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pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

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0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

<h3>245.66g of NH₄Cl is the mass we need to add to obtain the desire pH</h3>

<em />

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