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Harrizon [31]
3 years ago
8

A chemist must prepare of 800.0 ml potassium hydroxide solution with a pH of 13.00 at 25°.

Chemistry
1 answer:
ArbitrLikvidat [17]3 years ago
4 0

Answer:

4.48 grams is the mass of potassium hydroxide that the chemist must weigh out in the second step.

Explanation:

The pH of the solution = 13.00

pH + pOH = 14

pOH = 14 - pH = 14 - 13.00 = 1.00

pOH=-\log[OH^-]

1.00=-\log[OH^-]

[OH^-]=10^{-1.00} M=0.100 M

KOH(aq)\rightarrow K^+(aq)+OH^-(aq)

[KOH]=[OH^-]=[K^+]=0.100 M

Molariy of the KOH = 0.100 M

Volume of the KOH solution = 800 mL= 0.800 L

1 mL = 0.001 L

Moles of KOH = n

Molarity=\frac{Moles}{Volume(L)}

0.100 M=\frac{n}{0.800 L}

n = 0.0800 mol

Mass of 0.0800 moles of KOH :

0.0800 mol × 56 g/mol = 4.48 g

4.48 grams is the mass of potassium hydroxide that the chemist must weigh out in the second step.

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Therefore, putting given values into the above formula as follows.

                  E = \frac{hc}{\lambda}

      4.645 \times 10^{-19} J = \frac{6.62 \times 10^{-34} Js \times 3 \times 10^{8} m/s}{\lambda}  

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Explanation:

1. Write the <em>chemical equation</em> for the reaction.

HNO₃ + KOH ⟶ KNO₃ + H₂O

===============

2. Calculate the <em>moles of HNO₃</em>

c = n/V                                               Multiply each side by V and transpose

n = Vc

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c = 0.1744 mol·L⁻¹                             Calculate the moles of HNO₃

Moles of HNO₃ = 0.027 86 × 0.1744

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===============

3. Calculate the <em>moles of KOH </em>

1 mol KOH ≡ 1 mol HNO₃                 Calculate the moles of KOH

Moles of KOH = 4.859 × 10⁻³× 1/1

Moles of KOH = 4.859 × 10⁻³ mol KOH

===============

4. Calculate the <em>molar concentration</em> of the KOH

V = 29.4 mL = 0.0294 L                   Calculate the concentration

c = 4.859 × 10⁻³/0.0294

c = 0.165 mol·L⁻¹

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