B I think is right. Hope this helps!
Is this a question or a statement?
Answer: 1. 
increases.
Explanation:
Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.
For the given equation:
If the concentration of 
is increased , according to the Le-Chatlier's principle, the reaction has to shift to right or forward direction. In order to do that the concentration of products has to increase.
Thus the concentration of increases.
Despite its appearance, air has a ‘thickness’ so when the sun is high in the sky the light travels through the air on a very much shorter path than when it is low on the horizon.
Imagine that air water and you are below the surface, the light from an overhead sun will be quite sharp and bright, but if lower in the sky it will have to travel through much more water to reach you, so will look less bright and sharp. It ma not seem the same, but the atmosphere is just like very thin water, and a low lying sun will be drastically reduced in strength, so all you will see is a sun with a shift to the red end of the spectrum as all the actinic part will be filtered away by that thicker atmosphere.
