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Inessa05 [86]
3 years ago
5

When a compound containing cesium ions is heated in a Bunsen burner flame, photons with an energy of 4.30 x 10-19 J are emitted.

What is the wavelength and color of the cesium flame?
Chemistry
1 answer:
inessss [21]3 years ago
6 0

<u>Answer:</u> The wavelength of the flame is 462 nm and color of cesium flame is blue.

<u>Explanation:</u>

To calculate the wavelength, we use Planck's equation, which is:

E=\frac{hc}{\lambda}

where,

E = Energy of 1 photon = 4.30\times 10^{-19}J

h = Planck's constant = 6.625\times 10^{-34}J.s

c = speed of light = 3\times 10^8m/s

\lambda = wavelength = ?

Putting values in above equation, we get:

4.30\times 10^{-19}=\frac{6.625\times 10^{-34}J.s\times 3\times 10^8m/s}{\lambda }\\\\\lambda=\frac{6.625\times 10^{-34}J.s\times 3\times 10^8m/s}{4.30\times 10^{-19}}=4.62\times 10^{-7}m=462nm

The range of wavelength of blue light lies in range of 500 nm - 435 nm

The calculated wavelength lies in the above range. So, the color of the cesium flame is 462 nm

Hence, the wavelength of the flame is 462 nm and color of cesium flame is blue.

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A 265-mL flask contains pure helium at a pressure of 751 torrs. A second flask with a volume of 465 mL contains pure argon at a
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Answer:

Total Pressure = 745.6 torr

Partial Pressure of He = 272.8 torr

Partial Pressure of Ar =  472.8 torr

Explanation:

Step 1: Data given

Volume of the flask helium = 265 mL

Pressure in the helium flask = 751 torr = 751/760 atm

Volume of the flask argon = 465 mL

Pressure in the argon flask = 727 torr = 727/760 atm

The total pressure exerted by a gaseous mixture is equal to the sum of the partial pressures of each individual component in a gas mixture.

Step 2: Calculate total volume

Total volume = 265 mL + 465 mL = 730 mL =  0.730 L

Step 3: Boyle's Law:

P1V1=P2V2

⇒ with P1 = total pressure gas exerts in its own flask

 ⇒ with V1 = volume of flask with stopcock valve closed

 ⇒ with P2 = partial pressure of gas exerts on total volume of both flasks when stopcock valve is opened  

 ⇒ with V2 = total volume of both flasks with stopcock valve opened

Helium using Boyle's Law equation from above:

P1V1=P2V2

⇒ with P1 = Pressure of helium = 751 /760 = 0.98816 atm

 ⇒ with V1 = volume of helium = 0.265 L

 ⇒ with P2 = The new partial pressure of helium

 ⇒ with V2 = total volume = 0.730 L

(0.98816 atm)(0.265L)=P2(0.730L)

P2=0.359 atm

Argon using Boyle's Law equation from above:

P1V1=P2V2

⇒ with P1 = Pressure of argon = 727/760 = 0.95658 atm

 ⇒ with V1 = volume of argon = 0.465 L

 ⇒ with P2 = The new partial pressure of argon

 ⇒ with V2 = total volume = 0.730 L

(0.95658 atm)(0.465L)=P2(0.730L)

P2=0.609 atm

Step 4: Convert pressure in atm to torr

Pressure helium = 0.359 atm = 272.8 torr

Pressure argon = 0.609 atm = 472.8 torr

Step 5: Calculate Total pressure

Ptotal = P(He)+P(Ar)

⇒ Pt  = total pressure of the gas mixture

⇒ P(He) = partial pressure of Helium

 ⇒ P(Ar)  = partial pressure of Argon

Pt = 272.8 torr + 472.8 torr

Pt = 745.6 torr

Total Pressure = 745.6 torr

Partial Pressure of He = 272.8 torr

Partial Pressure of Ar =  472.8 torr

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