Suppose a 250. mL flask is filled with 0.30 mol of N_2 and 0.70 mol of NO. The following reaction becomes possible:N_2(g) +O2 →
1 answer:
Answer:
0.4 M
Explanation:
Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.
Because there's no O₂ in the beginning, the NO will decompose:
N₂(g) + O₂(g) ⇄ 2NO(g)
0.30 0 0.70 Initial
+x +x -2x Reacts (the stoichiometry is 1:1:2)
0.30+x x 0.70-2x Equilibrium
The equilibrium concentrations are the number of moles divided by the volume (0.250 L):
[N₂] = (0.30 + x)/0.250
[O₂] = x/0.25
[NO] = (0.70 - 2x)/0.250
K = [NO]²/([N₂]*[O₂])
K =
7.70 = (0.70-2x)²/[(0.30+x)*x]
7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)
4x² - 2.80x + 0.49 = 2.31x + 7.70x²
3.7x² + 5.11x - 0.49 = 0
Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70
x = 0.09 mol
Thus,
[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M
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Answer:
Explanation:
We have three equations:
1. 2H₂S(g) + O₂(g) ⟶ 2S(s, rhombic) + 2H₂O(g) ; ∆H = -442.4 kJ
2. S(s, rhombic) + O₂(g) ⟶ SO₂(g); ∆H = -296.8 kJ
3. PbO(s) + H₂S(g) ⟶ PbS(s) + SO₂(g); ∆H = -104.3 kJ
From these, we must devise the target equation:
4. 2PbS(s) + 3O₂(g) ⟶2PbO(s) + 2SO₂(g); ΔH = ?
The target equation has PbS(s) on the left, so you reverse Equation 3 and double it.
When you reverse an equation, you reverse the sign of its ΔH.
When you double an equation, you double its ΔH.
5. 2PbS(s) + 2H₂O(g) ⟶ 2PbO(s) + 2H₂S(g); ∆H = 208.6 kJ
Equation 5 has 2H₂O on the left. That is not in the target equation.
You need an equation with 2H₂O on the right, so you copy Equation 1.
6. 2H₂S(g) + O₂(g) ⟶ 2S(s, rhombic) + 2H₂O(g) ; ∆H = -442.4 kJ
Equation 6 has 2S(s, rhombic) on the right. That is not in the target equation.
You need an equation with 2S(s, rhombic) on the left, so you double Equation 2.
7. 2S(s, rhombic) + 2O₂(g) ⟶ 2SO₂(g); ∆H = -593.6 kJ
Now, you add equations 5, 6, and 7, cancelling species that appear on opposite sides of the reaction arrows.
When you add equations, you add their ΔH values.
You get the target equation 4:
5. 2PbS(s) + <u>2H₂O(g</u>) ⟶ 2PbO(s) + <u>2H₂S(g</u>); ∆H = 208.6 kJ
6. <u>2H₂S(g)</u> + O₂(g) ⟶ <u>2S(s</u>) + <u>2H₂O(g)</u> ; ∆H = -442.4 kJ
<u>7</u><u>. </u><u>2S(s)</u><u> + 2O₂(g) ⟶ 2SO₂(g); ∆H = -593.6 kJ </u>
4 . 2PbS(s) + 3O₂(g) ⟶ 2PbO(s) + 2SO₂(g); ΔH = -827.4 kJ
Answer:
The structures are attached in file.
Hydrogen bonding and intermolecular forces is the reason for ranks allotted.
Explanation:
In determining Lewis structure, we calculate the overall number of valence electrons available for bonding. Making carbon (the least electronegative atom) the central atom in the structure, we allocate valence electrons until each atom has achieved stability.
In order of decreasing affinity to water molecules:
This is due to the fact that the will accept protons more readily than the bicarbonate ion,
. Carbonic acid,
will not accept any more protons, hence it is the least attractive to water molecule, even though soluble.
Answer: Molarity of anions in the chemist's solution is 0.0104 M
Explanation:
Molarity : It is defined as the number of moles of solute present per liter of the solution.
Formula used :
where,
n= moles of solute
= volume of solution in ml = 100 ml
Now put all the given values in the formula of molarity, we get
Therefore, the molarity of solution will be
As 1 mole of gives 2 moles of
Thus moles of
gives =
Thus the molarity of anions in the chemist's solution is 0.0104 M