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Bad White [126]
3 years ago
7

Suppose a 250. mL flask is filled with 0.30 mol of N_2 and 0.70 mol of NO. The following reaction becomes possible:N_2(g) +O2 →

2NO(g)a. The equilibrium constant K for this reaction is 7.70 at the temperature of the flask.b. Calculate the equilibrium molarity of O2. Round your answer to one decimal place.
Chemistry
1 answer:
Inessa [10]3 years ago
3 0

Answer:

0.4 M

Explanation:

Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.

Because there's no O₂ in the beginning, the NO will decompose:

N₂(g) + O₂(g) ⇄ 2NO(g)

0.30 0 0.70 Initial

+x +x -2x Reacts (the stoichiometry is 1:1:2)

0.30+x x 0.70-2x Equilibrium

The equilibrium concentrations are the number of moles divided by the volume (0.250 L):

[N₂] = (0.30 + x)/0.250

[O₂] = x/0.25

[NO] = (0.70 - 2x)/0.250

K = [NO]²/([N₂]*[O₂])

K = \frac{(\frac{0.70 -2x}{0.250})^2 }{\frac{0.30+x}{0.250}*\frac{x}{0.250} }

7.70 = (0.70-2x)²/[(0.30+x)*x]

7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)

4x² - 2.80x + 0.49 = 2.31x + 7.70x²

3.7x² + 5.11x - 0.49 = 0

Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70

x = 0.09 mol

Thus,

[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M

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(b) 28.91 g.

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∴ m = (no. of moles of solute)/(mass of water (kg))

<em>∴ m = (mass/molar mass of solute)/(mass of water (kg)).</em>

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<u><em>(a) Calculate the mass of CaCl₂·6H₂O needed to prepare 0.125 m CaCl₂(aq) by using 500. g of water.</em></u>

∵ m = (mass/molar mass of CaCl₂·6H₂O)/(mass of water (kg)).

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∴ 0.125 m = (mass of CaCl₂·6H₂O / 219.0757 g/mol)/(0.5 kg).

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