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Bad White [126]
3 years ago
7

Suppose a 250. mL flask is filled with 0.30 mol of N_2 and 0.70 mol of NO. The following reaction becomes possible:N_2(g) +O2 →

2NO(g)a. The equilibrium constant K for this reaction is 7.70 at the temperature of the flask.b. Calculate the equilibrium molarity of O2. Round your answer to one decimal place.
Chemistry
1 answer:
Inessa [10]3 years ago
3 0

Answer:

0.4 M

Explanation:

Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.

Because there's no O₂ in the beginning, the NO will decompose:

N₂(g) + O₂(g) ⇄ 2NO(g)

0.30 0 0.70 Initial

+x +x -2x Reacts (the stoichiometry is 1:1:2)

0.30+x x 0.70-2x Equilibrium

The equilibrium concentrations are the number of moles divided by the volume (0.250 L):

[N₂] = (0.30 + x)/0.250

[O₂] = x/0.25

[NO] = (0.70 - 2x)/0.250

K = [NO]²/([N₂]*[O₂])

K = \frac{(\frac{0.70 -2x}{0.250})^2 }{\frac{0.30+x}{0.250}*\frac{x}{0.250} }

7.70 = (0.70-2x)²/[(0.30+x)*x]

7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)

4x² - 2.80x + 0.49 = 2.31x + 7.70x²

3.7x² + 5.11x - 0.49 = 0

Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70

x = 0.09 mol

Thus,

[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M

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Here I found some info at Yahoo answers: https://answers.yahoo.com/question/index?qid=20090119191941AAB7oAb
The more electronegative an atom is the more unwilling it is to lose its electrons in a compound. If you do try to take a very EN atom away from a compound you'll need to apply a lot of energy for that to happen. I can give an example of a single atom though 

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3 years ago
2. Calculate the atomic mass of an element that has two isotopes, each with 50.00% abundance. One isotope has a mass of 63.00 am
melamori03 [73]

Answer:

The atomic mass of element is 65.5 amu.

Explanation:

Given data:

Abundance of X-63 = 50.000%

Atomic mass of  X-63 = 63.00 amu

Atomic mass of X-68 = 68.00 amu

Atomic mass of element = ?

Solution:

Abundance of X-68 = 100-50 = 50%

Average atomic mass = (abundance of 1st isotope × its atomic mass) +(abundance of 2nd isotope × its atomic mass)  / 100

Average atomic mass  = (50×63)+(50×68) /100

Average atomic mass =  3150 + 3400 / 100

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Average atomic mass = 65.5 amu.

The atomic mass of element is 65.5 amu.

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6 0
2 years ago
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Phosgene, COCl2, gained notoriety as a chemical weapon in World War I. Phosgene is produced by the reaction of carbon monoxide w
jek_recluse [69]

The question is incomplete, here is the complete question:

Phosgene, COCl_2, gained notoriety as a chemical weapon in World War I. Phosgene is produced by the reaction of carbon monoxide with chlorine:  

CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)

The value of K_c for this reaction is 5.79 at 570 K. What are the equilibrium partial pressures of the three gases if a reaction vessel initially contains a mixture of the reactants in which p_{CO}=p_{Cl_2}=0.265atm and p_{COCl_2}=0.000atm ?

<u>Answer:</u> The equilibrium partial pressure of CO, Cl_2\text{ and }COCl_2 is 0.257 atm, 0.257 atm and 0.008 atm respectively.

<u>Explanation:</u>

The relation of K_c\text{ and }K_p is given by:

K_p=K_c(RT)^{\Delta n_g}

K_p = Equilibrium constant in terms of partial pressure

K_c = Equilibrium constant in terms of concentration = 5.79

\Delta n_g = Difference between gaseous moles on product side and reactant side = n_{g,p}-n_{g,r}=1-2=-1

R = Gas constant = 0.0821\text{ L. atm }mol^{-1}K^{-1}

T = Temperature = 570 K

Putting values in above equation, we get:

K_p=5.79\times (0.0821\times 570)^{-1}\\\\K_p=0.124

We are given:

Initial partial pressure of CO = 0.265 atm

Initial partial pressure of chlorine gas = 0.265 atm

Initial partial pressure of phosgene = 0.00 atm

The given chemical equation follows:

                      CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)

<u>Initial:</u>            0.265      0.265

<u>At eqllm:</u>        0.265-x    0.265-x        x

The expression of K_p for above equation follows:

K_p=\frac{p_{COCl_2}}{p_{CO}\times p_{Cl_2}}

Putting values in above equation, we get:

0.124=\frac{x}{(0.265-x)\times (0.265-x)}\\\\x=0.0082,8.59

Neglecting the value of x = 8.59 because equilibrium partial pressure cannot be greater than initial pressure

So, the equilibrium partial pressure of CO = (0.265-x)=(0.265-0.008)=0.257atm

The equilibrium partial pressure of Cl_2=(0.265-x)=(0.265-0.008)=0.257atm

The equilibrium partial pressure of COCl_2=x=0.008atm

Hence, the equilibrium partial pressure of CO, Cl_2\text{ and }COCl_2 is 0.257 atm, 0.257 atm and 0.008 atm respectively.

6 0
3 years ago
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Fantom [35]

The answer of the the reaction between tetrabromoethane and zinc is the image below. Acetylene and two zinc bromide are formed

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