Answer:
A reaction is non-spontaneous at any temperature when the Gibbs free energy > 0.
Explanation:
There is a state function, that determines if a reaction is sponaneous or non spontaneous:
ΔG = Gibbs free energy
A reaction is non spontaneous when it does require energy to produce that reaction. It will be spontaneous, when the reaction does not require energy to be occured.
The formula is: ΔG = ΔH - T.ΔS
ΔH → Enthalpy → Energy gained or realeased as heat.
ΔH < 0 → <em>Exothermic reaction. Spontaneity is favored
</em>
T → Temperature
ΔS → Entropy → Degree of disorder of a system.
When the system has a considered disorder ΔS > 0, disorder increases.
When the system is more ordered, ΔS < 0, disorder decreases.
The reaction will be non spontaneous if, the enthalpy is positive (endothermic reaction) and the ΔS < 0 (disorder decreases). It will not occur if we do not give energy.
ΔG < 0 → Spontaneous reaction
ΔG > 0 → Non spontaneous reaction
ΔG = 0 → System in equilibrium
Because the resulting hybridized orbitals are more stable
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Answer:1) It is due to large cohesive force acting between the molecules of mercury that the droplets of mercury when brought in contact pulled together to form a bigger drop in order to make potential energy minimum. The temperature of this bigger drop increases since the total surface area decreases.
2) A spherical shape has the minimum surface area to volume ratio of all geometric forms. When two drops of a liquid are brought in contact, the cohesive forces between their molecules coalesce the drops into a single larger drop. This is because, the volume of the liquid remaining the same, the surface area of the resulting single drop is less than the combined surface area of the smaller drops. The resulting decrease in surface energy is released into the environment as heat.
Answer:
C. I, III , IV
Explanation:
As we move from left to right across the periodic table the number of valance electrons in an atom increase. The atomic size tend to decrease in same period of periodic table because the electrons are added with in the same shell. When the electron are added, at the same time protons are also added in the nucleus. The positive charge is going to increase and this charge is greater in effect than the charge of electrons. This effect lead to the greater nuclear attraction. The electrons are pull towards the nucleus and valance shell get closer to the nucleus. As a result of this greater nuclear attraction atomic radius decreases and ionization energy increases because it is very difficult to remove the electron from atom and more energy is required.
As we move down the group atomic radii increased with increase of atomic number. The addition of electron in next level cause the atomic radii to increased. The hold of nucleus on valance shell become weaker because of shielding of electrons thus size of atom increased.
As the size of atom increases the ionization energy from top to bottom also decreases because it becomes easier to remove the electron because of less nuclear attraction and as more electrons are added the outer electrons becomes more shielded and away from nucleus.
