what would you observe if you used a ballpoint pen instead of a pencil to mark the chromatography paper?

Chemistry

1 answer:

sveticcg [70]3 years ago

3 0

Answer:

It basically messes up the results

Explanation:

Pen ink consists of resins, pigments and other colouring dyes dissolved in appropriate solvents like propylene glycol, propyl alcohol and some other ethers. If the ball point pen is used to mark on the chromatography paper then these pigments will also move along with the solvent and interfere with the spots of our analyte.

If you use a ball point pen when doing a chromatogram, then the ink would separate as it is a mixture and run down the paper.

Graphite, or pencil lead however, is not an organic material and therefore will not be affected by common organic solvents used for thin-layer chromatography. Pen ink on the other hand will be readily absorbed by the solvent and will move up the plate.

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A civil engineering student is considering buying an electric car. However, the conscious student wants to make sure her carbon

svetlana [45]

Answer:

$\text{An gasoline-powered vehicle has }\\\boxed{\text{five times the carbon footprint}}\text{ of an electric vehicle.}$

Explanation:

1. Miles travelled in an average month

$\text{Miles} = \text{1 mo} \times \dfrac{\text{52 wk}}{\text{12 mo}} \times \dfrac{\text{5 da}}{\text{1 wk}} \times \dfrac{\text{16 mi}}{\text{1 da}} = \text{347 mi}$

2. Using a gasoline powered vehicle

(a) Moles of heptane used

$n = \text{347 mi} \times \dfrac{\text{1 gal}}{\text{36.5 mi}}\times \dfrac{\text{3.785 L}}{\text{1 gal}} \times \dfrac{\text{679.5 g}}{\text{1L}} \times \dfrac{ \text{1 mol}}{\text{100.20 g}}= \text{244 mol}$

(b) Equation for combustion

C₇H₁₆ + O₂ ⟶ 7CO₂ + 8H₂O

(c) Moles of CO₂ formed

$n = \text{244 mol heptane} \times \dfrac{\text{7 mol CO$_{2}$}}{\text{1 mol heptane}} = \text{1710 mol CO$_{2}$}$

(d) Volume of CO₂ formed

At 20 °C and 1 atm, the molar volume of a gas is 24.0 L.

$V = \text{1710 mol } \times \dfrac{\text{24.0 L}}{\text{1 mol}} \times \dfrac{\text{1 gal}}{\text{3.785 L}} = \textbf{10 800 gal}$

3. Using an electric vehicle

(a) Theoretical energy used

$\text{Theor. Energy} = \text{347 mi} \times \dfrac{\text{1 kWh}}{\text{5.2 mi}} = \text{66.7 kWh theor.}$

(b) Actual energy used

The power station is only 85 % efficient.

$\text{Actual energy used} = \text{66.7 kWh theor.} \times \dfrac{\text{100 kWh actual}}{\text{ 85 kWh theor.}}\times \dfrac{\text{3600 kJ}}{\text{1 kWh}}\\\\ = 2.82\times 10^{5} \text{ kJ}\$

(c) Combustion of CH₄

CH₄ + 2O₂ ⟶ CO₂ +2 H₂O

(d) Equivalent volume of CO₂

The heat of combustion of methane is -802.3 kJ·mol⁻¹

$V= 2.82\times 10^{5}\text{ kJ} \times \dfrac{\text{1 mol methane}}{\text{802.3 kJ}} \times \dfrac{\text{1 mol CO$_{2}$} }{\text{1 mol methane}} \times \dfrac{ \text{24.0 L}}{ \text{1 mol CO$_{2}$}}\\\\ \times \dfrac{\text{1 gal}}{\text{3.875 L}} = \textbf{2180 gal}$

4. Comparison

$\dfrac{V_{\text{gasoline}}}{V_{\text{electric}}} = \dfrac{10800}{2180} = 5.0\\\\ \text{An gasoline-powered vehicle has }\\ \boxed{\textbf{ five times the carbon footprint}}\text{ of an electric vehicle.}$