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2 years ago

Question 1: Which of the following statement is false about conjugated systems?

Chemistry

1 answer:

valkas [14]2 years ago

8 0

Answer:

A conjugated system can only contain two alkenes: False

B. A cumulated diene is less stable than an isolated diene.

False

Explanation:

A. A conjugated system is more stable than an unconjugated system.: True

Due to resonance a conjugated system is more stable.

B. The s-trans isomer is favored over the s-cis isomer.: True

Due to repulsion in s-cis isomer they are less stable.

C. A conjugated system has multiple resonance structures. True

This is the reason they are stable.

D. A conjugated system can only contain two alkenes: False

A conjugated system may have may alternate double and triple bonds.

2) A trans alkene releases less heat upon hydrogenation than a cis alkene.

True

Trans alkenes are more stable than cis alkene. Thus heat of hydrogenation of trans alkene is less than cis alkene.

B. A cumulated diene is less stable than an isolated diene.

False

C. Multiple products can always form when treated a conjugated diene with HBr. True

There can be 1,2 or 1,4 addition

D. Conjugated systems arise only between sp2-hybridized atoms.

True

Conjugation allows resonance which is possible in sp2 systems

E. Conjugated double bonds involve unhybridized p-orbitals aligned with each other

True

The double bond is formed as pi bond due to side ways overlapping of unhybridized p orbitals

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An inhibitor is added to an enzyme-catalyzed reaction at a concentration of 26.7 μM. The Vmax remains constant at 50.0 μM/s, but

fomenos

Using the Michaelis-Menten equation competitive inhibition, the Inhibition constant, Ki of the inhibitor is 53.4 μM.

<h3>What is the Ki for the inhibitor?</h3>

The Ki of an inhibitor is known as the inhibition constant.

The inhibition is a competitive inhibition as the Vmax is unchanged but Km changes.

Using the Michaelis-Menten equation for inhibition:

Kma = Km/(1 + [I]/Ki)

Making Ki subject of the formula:

Ki = [I]/{(Kma/Km) - 1}

where:

Kma is the apparent Km due to inhibitor
Km is the Km of the enzyme-catalyzed reaction
[I] is the concentration of the inhibitor

Solving for Ki:

where

[I] = 26.7 μM

Km = 1.0

Kma = (150% × 1 ) + 1 = 2.5

Ki = 26.7 μM/{(2.5/1) - 1)

Ki = 53.4 μM

Therefore, the Inhibition constant, Ki of the inhibitor is 53.4 μM.

Learn more about enzyme inhibition at: brainly.com/question/13618533

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2 years ago

11. If you weight 60 lbs on Earth, you would weigh<br> moon

DochEvi [55]

Answer:

about 10 pounds

Explanation:

your mass doesn't change but weight changes (due to gravity)

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3 years ago

Read 2 more answers

A solution contains [Ba2+] = 5.0 × 10−5 M, [Zn2+] = 2.0 × 10−7 M, and [Ag+] = 3.0 × 10−5 M. Sodium oxalate (Na2C2O4) is slowly a

Jet001 [13]

Answer:

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄

Explanation:

1. Calculate the equilibrium concentrations of oxalate ion

Let [C₂O₄²⁻] = c

(a) Barium oxalate

BaC₂O₄ ⇌ Ba²⁺ + C₂O₄²⁻

E/mol·L⁻¹: 5.0 × 10⁻⁵ c

Ksp = [Ba²⁺][C₂O₄²⁻] = 5.0 × 10⁻⁵c = 1.5 × 10⁻⁸

c = (1.5 × 10⁻⁸)/(5.0 × 10⁻⁵) = 3.0 × 10⁻⁴ mol·L⁻¹

(b) Zinc oxalate

ZnC₂O₄ ⇌ Zn²⁺ + C₂O₄²⁻

E/mol·L⁻¹: 2.0 × 10⁻⁷ c

Ksp = [Zn²⁺][C₂O₄²⁻] = 2.0 × 10⁻⁷c = 1.35 × 10⁻⁹

c = (1.35 × 10⁻⁹)/(2.0 × 10⁻⁷) = 6.8 × 10⁻³ mol·L⁻¹

(c) Silver oxalate

Ag₂C₂O₄ ⇌ 2Ag⁺ + C₂O₄²⁻

E/mol·L⁻¹: 3.0 × 10⁻⁵ c

Ksp = [Ag⁺]²[C₂O₄²⁻] = (3.0× 10⁻⁵)²c = 9.0 × 10⁻¹⁰c = 1.1 × 10⁻¹¹

c = (1.1 × 10⁻¹¹)/(9.0 × 10⁻¹⁰) = 0.012 mol·L⁻¹

2. Decide the order of precipitation

BaC₂O₄ will precipitate when c > 3.0 × 10⁻⁴ mol·L⁻¹

ZnC₂O₄ will precipitate when c > 6.8 × 10⁻³ mol·L⁻¹

Ag₂C₂O₄ will precipitate when c > 0.028 mol·L⁻¹

This happens to be the order of increasing concentration of oxalate ion.

The order of precipitation is

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄

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3 years ago

What is the electron configuration of an element with atomic number 15? A. 1s2 2s2 2p6 B. 1s2 2s2 2p6 3s2 3p5 C. 1s2 2s2 2p6 3s2

kipiarov [429]

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3 years ago

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Name the following compound: 2-ethyl-4-methylheptene 3,5-dimethyl-2-octene 2-ethyl-4-methylheptane 3-methyl-5-propyl-2-hexene

Nadusha1986 [10]

Answer:

3,5-dimethyl-2-octene

Explanation:

The parent chain will be choosen based on the highest value. In this case, if we count from top to bottom, we'll get seven carbon, however if we count from the second carbon, going left and then down, we'll get eight carbon. So the parent chain is octene

The double bond is located at the second carbon and the methyl groups are located on carbon 3 & 5. Since there are two methyl groups, we add di- in front of methyl to indicate two methyl groups present.

Note: The functional group has to be prioritise and it needed to be a part of the parent chain. In this case, the functional group is the double bond. (alkene)

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3 years ago