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jeka94
2 years ago
8

Balance each of the following in BASE: Show work

Chemistry
1 answer:
kupik [55]2 years ago
7 0

Answer : The balanced chemical equation in a basic solution are,

(A) 2CrO_4^{2-}+8H_2O+3Cu\rightarrow 2Cr(OH)_3+4OH^-+3Cu(OH)_2

(B) 2NO_2+2OH^-\rightarrow NO_3^-+H_2O+NO_2^-

(C) 4Zn+7OH^-+NO_3^-+6H_2O\rightarrow 4[Zn(OH)_4]^{2-}+NH_3

(D) Br_2+12OH^-+5Br_2\rightarrow 2BrO_3^-+6H_2O+10Br^-

Explanation :

<u>(A) The given chemical reaction is :</u>

CrO_4^{2-}(aq)+Cu(s)\rightarrow Cr(OH)_3(s)+Cu(OH)_2(s)

The oxidation-reduction half reaction will be :

Oxidation : Cu\rightarrow Cu^{2+}+2e^-

Reduction : CrO_4^{2-}+4H_2O+3e^-\rightarrow Cr^{3+}+8OH^-

In order to balance the electrons, we multiply the oxidation reaction by 3 and reduction reaction by 2 then added both equation, we get the balanced redox reaction.

The balanced chemical equation in a basic solution will be,

2CrO_4^{2-}+8H_2O+3Cu\rightarrow 2Cr^{3+}+16OH^-+3Cu^{2+}

or,

2CrO_4^{2-}+8H_2O+3Cu\rightarrow 2Cr(OH)_3+4OH^-+3Cu(OH)_2

<u>(B) The given chemical reaction is :</u>

NO_2(g)\rightarrow NO_3^-(aq)+NO_2^-(aq)

The oxidation-reduction half reaction will be :

Oxidation : NO_2+2OH^-\rightarrow NO_3^-+H_2O+1e^-

Reduction : NO_2+1e^-\rightarrow NO_2^-

The electrons in both the reactions are balanced. Now added both equation, we get the balanced redox reaction.

The balanced chemical equation in a basic solution will be,

2NO_2+2OH^-\rightarrow NO_3^-+H_2O+NO_2^-

<u>(C) The given chemical reaction is :</u>

Zn(s)+NO_3^-(aq)\rightarrow Zn(OH)_4^{2-}(aq)+NH_3(g)

The oxidation-reduction half reaction will be :

Oxidation : Zn+4OH^-\rightarrow [Zn(OH)_4]^{2-}+2e^-

Reduction : NO_3^-+6H_2O+8e^-\rightarrow NH_3+9OH^-

In order to balance the electrons, we multiply the oxidation reaction by 4 and then added both equation, we get the balanced redox reaction.

The balanced chemical equation in a basic solution will be,

4Zn+7OH^-+NO_3^-+6H_2O\rightarrow 4[Zn(OH)_4]^{2-}+NH_3

<u>(D) The given chemical reaction is :</u>

Br_2(l)\rightarrow BrO_3^-(aq)+Br^-(aq)

The oxidation-reduction half reaction will be :

Oxidation : Br_2+12OH^-\rightarrow 2BrO_3^-+6H_2O+10e^-

Reduction : Br_2+2e^-\rightarrow 2Br^-

In order to balance the electrons, we multiply the reduction reaction by 5 and then added both equation, we get the balanced redox reaction.

The balanced chemical equation in a basic solution will be,

Br_2+12OH^-+5Br_2\rightarrow 2BrO_3^-+6H_2O+10Br^-

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Enthalpy change is the difference between energy used and energy gained. The change in enthalpy of the liquid mercury is 0.0231 kJ.

<h3>What is the enthalpy change?</h3>

Enthalpy change is the difference between the energy used to break chemical bonds and the energy gained by the products formed in a chemical reaction.

The enthalpy change is given by,

\rm \Delta H_{rxn} = \rm q_{rxn}

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Given,

Mass of the liquid mercury (m) = 11.0 gm

The specific heat of mercury (c) = 0.14 J per g per degree Celsius

Temperature change = 15 degrees Celsius

Enthalpy change is calculated as:

\begin{aligned} \rm q &= \rm mc\Delta T\\\\&= 11 \times 0.14 \times 15\\\\&= 23.1 \;\rm J\end{aligned}

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A 7.0 g sample of a hydrocarbon (a molecule that has only hydrogen and carbon) is subject to combustion analysis. The mass of CO
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Answer: The empirical formula for the given compound is CH_2

Explanation:

The chemical equation for the combustion of compound having carbon and hydrogen follows:

C_xH_y+O_2\rightarrow CO_2+H_2O

where, 'x' and 'y' are the subscripts of carbon and hydrogen respectively.

We are given:

Mass of CO_2=22.0g

We know that:

Molar mass of carbon dioxide = 44 g/mol

For calculating the mass of carbon:

In 44 g of carbon dioxide, 12 g of carbon is contained.

So, in 22.0 g of carbon dioxide, \frac{12}{44}\times 22.0=6g of carbon will be contained.

For calculating the mass of hydrogen:

Mass of hydrogen = Mass of sample - Mass of carbon

Mass of hydrogen = 7.0 g - 6 g

Mass of hydrogen = 1.0 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{6g}{12g/mole}=0.5moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{1.0g}{1g/mole}=1.0moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.5 moles.

For Carbon = \frac{0.5}{0.5}=1

For Hydrogen  = \frac{1.0}{0.5}=2

Step 3: Taking the mole ratio as their subscripts.

The ratio of Fe : C : H = 1 : 2

Hence, the empirical formula for the given compound is C_{1}H_{2}=CH_2

4 0
3 years ago
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