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4 years ago

Examine the nuclear reaction: 1 1 H+ 1 0 n -> 2 1 H.

1 answer:

6 0

1) Conversion of an isotope one chemical element or an isotope into another chemical element is called as nuclear transmutation.

2) In a nuclear transmutation reactions can be achieved either due to radioactive decay or due to nuclear reactions.

3) In this technique, it is possible to convert a stable element into radioactive atom by bombarding in with high speed particles. The initial stable nuclei is referred as parent nuclei, the fast moving particle is referred as projectile while new element which is formed is called as daughter element.

4) In the present reaction:
1 1 H+ 1 0 n -> 2 1 H
1 1H is a parent nuclei which is bombarded with the fast moving projectile
(1 0 n) to generate a new daughter nuclei (2 1H).

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CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at 25 ∘C under these conditions: PCO2PCCl4PCOCl2===0.140 atm0.185 atm0.7

padilas [110]

Answer: The $\Delta G$ for the reaction is 54.425 kJ/mol

Explanation:

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.735atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.185atm$

Putting values in above equation, we get:

$K_p=\frac{(0.735)^2}{0.410\times 0.185}\\\\K_p=20.85$

To calculate the gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 20.85

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(20.85))\\\\\Delta G=54425.26J/mol=54.425kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.425 kJ/mol

7 0

3 years ago

HNO3 + H2SO4 + NO

77julia77 [94]

Explanation:

The two half equations are;

3e + HNO3 → NO

S→ H2SO4 + 6e

When balancing half equations, we have to make sure the number of electrons gained is equal to the number of electrons lost.

Which factor will you use for the top equation?

We multiply by 2 to make the number of electrons = 6e

Which factor will you use for the bottom equation?

We multiply by 1 to make the number of electrons = 6e

3 0

3 years ago

Scientists are attempting to determine the composition of an unknown compound. The compound has a high melting point and is a go

zlopas [31]

Answer C

Explanation:

I took the test

3 0

3 years ago

Which of the following reactions have a positive ΔSrxn? Check all that apply.

PolarNik [594]

Answer:

The reactions that have a positive ΔS rxn are the first and the fourth choices:

2A(g) + B(s) → 3C(g)

2A(g) + 2B(g) → 5C(g)

Explanation:

ΔS rxn is the change of entropy of the chemical reaction.

ΔS rxn = S after reaction - S before reaction.

Therefore, a positive ΔS rxn means that the entropy after the reaction is greater than the entropy before the reaction.

You may use some assumptions to predict whether a reaction will lead an increase or decrease of the entropy.

First, assume that all the non-shown conditions, such as temperature and pressure, are constant.

Under that assumption, and from the meaning of entropy as a measure of the disorder or randomness of a system you can predict the sign of the change of entropy.

2A(g) + B(s) → 3C(g)

1) The solid compounds, B(s) in this case, are very ordered and so they have low entropy.

2) Gas molecules are highly disordered (scattered), and the greater the number of molecules of the gas the larger the entropy, S).

Hence, since the product side shows 3 gas molecules and the reactant side shows 2 gas molecules and 1 solid molecule, you predict that the products have a larger entropy than the reactants, meaning an increase in entropy: ΔS rxn is positive.

2A(g) + B(g) → C(g)

Using the same reasoning, 3 gas molecules in the reactant side have more entropy than 1 molecule in the product side, and so the reaction leads to a decrease in the entropy: ΔS rxn is negative

A(g) + B(g) → C(g)

Again, 2 gas molecules in the reactant side have more entropy than 1 molecule in the product side, and so the reaction leads to a decrease in the entropy: ΔS rxn is negative

2A(g) + 2B(g) → 5C(g)

With the same reasoing, 5 molecules in the product side, lets you predict that will have more entropy than 4 molecules in the reactant side, and, the entropy will increase: ΔS rxn is positive.

6 0

4 years ago

When hydrogen is combined with a metal, it has an oxidation number of _____.

solmaris [256]

The answer is c because thats the number when combined with a metal. +1 is when its combined with a nonmetal.

8 0

3 years ago