The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
Sodium borohydride is a relatively selective reducing agent Ethanolic solutions of Sodium borohydride reduces aldehyde , and ketone , in the presence of acid chloride , ester , epoxide , lactones , acids , nitriles , nitro groups.
The sodium borohydride does not reduce ester group because sodium borohydride is not strong enough and the electrophilicity at carbony carbon of ester is not more as compare toaldehyde , and ketone
The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
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Answer:
0.1593 L.
Explanation:
- We can use the general law of ideal gas: PV = nRT.
where, P is the pressure of the gas in atm.
V is the volume of the gas in L.
n is the no. of moles of the gas in mol.
R is the general gas constant,
T is the temperature of the gas in K.
- If n and P are constant, and have two different values of V and T:
<em>P₁V₁T₂ = P₂V₂T₁</em>
<em></em>
P₁ = 600 torr/760 = 0.789 atm, V₁ = 185.0 mL = 0.185 L, T₁ = 25.0°C + 273 = 298.0 K.
P₂ (at STP) = 1.0 atm, V₂ = ??? L, T₂ (at STP = 0.0°C) = 0.0°C + 273 = 273.0 K.
<em>∴ V₂ = P₁V₁T₂/P₂T₁</em> = (0.789 atm)(0.185 mL)(298.0 K)/(1.0 atm)(273.0 K) = <em>0.1593 L.</em>
<u>Answer:</u> The correct answer is Option A.
<u>Explanation:</u>
Electronegativity is defined as the tendency of an atom to attract the shared pair of electrons towards itself whenever a bond is formed.
This property increases as we move from left to right across a period because the number of charge on the nucleus gets increased and electrons are attracted more towards the nucleus.
This property decreases as we move from top to bottom in a group because the electrons get add up in the new shells which make them further away from the nucleus.
Thus, the correct answer is Option A.
