Thermodynamics, Nuclear Physics, Quantum Physics, Astronomy and Astrophysics
Answer:
2) 14.5 moles
Explanation:
The balanced chemical reaction for the formation is:
If 14.5 moles of are produced, is needed to use the stoichiometry of the chemical reaction to calculate how many moles of reacted to form this quantity:
Therefore 14.5 moles of are produced by 14.5 moles of
Answer:
C. The lowest-energy electron configuration of an atom has the maximum number of unpaired electrons, all of which have the same spin, in degenerate orbitals.
Explanation:
The Hund's rule is used to place the electrons in the orbitals is it states that:
1. Every orbital in a sublevel is singly occupied before any orbital is doubly occupied;
2. All of the electrons in singly occupied orbitals have the same spin.
So, the electrons first seek to fill the orbitals with the same energy (degenerate orbitals) before paring with electrons in a half-filled orbital. Orbitals doubly occupied have greater energy, so the lowest-energy electron configuration of an atom has the maximum number of unpaired electrons, and for the second statement, they have the same spin.
The other alternatives are correct, but they're not observed by the Hund's rule.
Part (a) :
H₂(g) + I₂(s) → 2 HI(g)
From given table:
G HI = + 1.3 kJ/mol
G H₂ = 0
G I₂ = 0
ΔG = G(products) - G(reactants) = 2 (1.3) = 2.6 kJ/mol
Part (b):
MnO₂(s) + 2 CO(g) → Mn(s) + 2 CO₂(g)
G MnO₂ = - 465.2
G CO = -137.16
G CO₂ = - 394.39
G Mn = 0
ΔG = G(products) - G(reactants) = (1(0) + 2*-394.39) - (-465.2 + 2*-137.16) = - 49.3 kJ/mol
Part (c):
NH₄Cl(s) → NH₃(g) + HCl(g)
ΔG = ΔH - T ΔS
ΔG = (H(products) - H(reactants)) - 298 * (S(products) - S(reactants))
= (-92.31 - 45.94) - (-314.4) - (298 k) * (192.3 + 186.8 - 94.6) J/K
= 176.15 kJ - 84.78 kJ = 91.38 kJ