B when is spins it means its rotating east and west directions
To solve this problem we will apply the concepts of Boiling Point elevation and Freezing Point Depression. The mathematical expression that allows us to find the temperature range in which these phenomena occur is given by
Boiling Point Elevation

Here,
= Constant ( Different for each solvent)
m = Molality
Freezing Point Depression

Here,
Constant ( Different for each solvent)
m = Molality
According to the statement we have that


From the two previous relation we can find the ratio between them, therefore



We already know the change in the freezing point, then



The temperature difference in the boiling point is 100°C (Aqueous solution), therefore


Therefore the boiling point of an aqueous solution is 