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3 years ago

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In a redox reaction, which particles are lost and gained in equal numbers

1 answer:

Anna35 [415]3 years ago

5 0

In a redox reaction electrons are lost and gained in equal numbers. The species that is oxidized gives electrons to the species that is reduced. I hope this helps. Let me know if anything is unclear.

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A 0.500-g sample of KCl is added to 50.0g of water in a calprimeter (Figure 5.12) If the temperature decreases by 1.05C. what is

Sauron [17]

Answer : The reaction is endothermic.

Explanation :

Formula used :

$Q=m\times c\times \Delta T$

where,

$\Delta T$ = change in temperature = $1.05^oC$

Q = heat involved in the dissolution of KCl = ?

m = mass = 0.500 + 50.0 = 50.5 g

c = specific heat of resulting solution = $4.18J/g^oC$

Now put all the given value in the above formula, we get:

$Q=50.5g\times 4.18J/g^oC\times 1.05^oC$

$Q=+221.64J$

The heat involved in the dissolution of KCl is positive that means as the change in temperature decreases then the reaction is endothermic and as the change in temperature increases then the reaction is exothermic.

Hence, the reaction is endothermic.

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3 years ago

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List the elements and the amounts of each element below for 5 Li2S04.

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Which of the following is an adaptation found in many desert plants? A. large, flat leaves B. dormant period during the winter C

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Consider the following reaction: CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at25 ∘C under these conditions: PCO2PCC

Salsk061 [2.6K]

<u>Answer:</u> The $\Delta G$ for the reaction is 54.6 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.760atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.180atm$

Putting values in above equation, we get:

$K_p=\frac{(0.760)^2}{0.140\times 0.180}\\\\K_p=22.92$

To calculate the Gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 22.92

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(22.92))\\\\\Delta G=54659.78J/mol=54.6kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.6 kJ/mol

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3 years ago