D IS THE ANSWER TO YOUR QUESTION
Explanation:
The reaction equation will be as follows.

Calculate the amount of
dissolved as follows.

It is given that
= 0.032 M/atm and
=
atm.
Hence,
will be calculated as follows.
=
= 
= 
or, = 
It is given that 
As, ![K_{a} = \frac{[H^{+}]^{2}}{[CO_{2}]}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BH%5E%7B%2B%7D%5D%5E%7B2%7D%7D%7B%5BCO_%7B2%7D%5D%7D)
= 
= 
Since, we know that pH = ![-log [H^{+}]](https://tex.z-dn.net/?f=-log%20%5BH%5E%7B%2B%7D%5D)
So, pH = 
= 5.7
Therefore, we can conclude that pH of water in equilibrium with the atmosphere is 5.7.
Answer:
![K_2=\frac{[NOBr]^4_{eq}}{[NO]^4_{eq}[Br]^2_{eq}}](https://tex.z-dn.net/?f=K_2%3D%5Cfrac%7B%5BNOBr%5D%5E4_%7Beq%7D%7D%7B%5BNO%5D%5E4_%7Beq%7D%5BBr%5D%5E2_%7Beq%7D%7D)
Explanation:
Hello,
In this case, for the equilibrium condition, the equilibrium constant is defined via the law of mass action, which states that the division between the concentrations of the products over the concentration of the reactants at equilibrium equals the equilibrium constant, for the given reaction:

The suitable equilibrium constant turns out:
![K_2=\frac{[NOBr]^4_{eq}}{[NO]^4_{eq}[Br]^2_{eq}}](https://tex.z-dn.net/?f=K_2%3D%5Cfrac%7B%5BNOBr%5D%5E4_%7Beq%7D%7D%7B%5BNO%5D%5E4_%7Beq%7D%5BBr%5D%5E2_%7Beq%7D%7D)
Or in terms of the initial equilibrium constant:

Since the second reaction is a doubled version of the first one.
Best regards.
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Hope that helped