A. Use average bond energies together with the standard enthalpy of formation of C(g) (718.4 kJ/mol ) to estimate the standard e
nthalpy of formation of gaseous benzene, C6H6(g). (Remember that average bond energies apply to the gas phase only.)
B. Compare the value you obtain using average bond energies to the actual standard enthalpy of formation of gaseous benzene, 82.9 kJ/mol. What does the difference between these two values tell you about the stability of benzene?
B. Compare the value you obtain using average bond energies to the actual standard enthalpy of formation of gaseous benzene, 82.9 kJ/mol. What does the difference between these two values tell you about the stability of benzene?
1 answer:
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Answer:
Reagent O₂ will be consumed first.
Explanation:
The balanced reaction between O₂ and C₄H₁₀ is:
2 C₄H₁₀ + 13 O₂ → 8 CO₂ + 10 H₂O
Then, by reaction stoichiometry, the following amounts of reactants and products participate in the reaction:
- C₄H₁₀: 2 moles
- O₂: 13 moles
- CO₂: 8 moles
- H₂O: 10 moles
Being:
- C: 12 g/mole
- H: 1 g/mole
- O: 16 g/mole
The molar mass of the compounds that participate in the reaction is:
- C₄H₁₀: 4*12 g/mole + 10*1 g/mole= 58 g/mole
- O₂: 2*16 g/mole= 32 g/mole
- CO₂: 12 g/mole + 2*16 g/mole= 44 g/mole
- H₂O: 2*1 g/mole + 16 g/mole= 18 g/mole
Then, by reaction stoichiometry, the following mass quantities of reactants and products participate in the reaction:
- C₄H₁₀: 2 moles* 58 g/mole= 116 g
- O₂: 13 moles* 32 g/mole= 416 g
- CO₂: 8 moles* 44 g/mole= 352 g
- H₂O: 10 moles* 18 g/mole= 180 g
If 78.1 g of O₂ react, it is possible to apply the following rule of three: if by stoichiometry 416 g of O₂ react with 116 g of C₄H₁₀, 62.4 g of C₄H₁₀ with how much mass of O₂ do they react?
mass of O₂= 223.78 grams
But 21.78 grams of O₂ are not available, 78.1 grams are available. Since you have less mass than you need to react with 62.4 g of C₄H₁₀, <u><em>reagent O₂ will be consumed first.</em></u>