Answer:
CH4(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]
Explanation:
Firstly, we must remember that the substitution reaction between halogens and alkanes to yield halogenoalkanes does not proceed by ionic mechanism rather it proceeds by free radical mechanism.
Now, if we look at the rate determining step as shown in the question, the elementary reaction equation of that step is not balanced.
Hence, the correct elementary reaction equation for the rate determining step and the rate law is; CH4(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]
Answer:
Option C is correct
Explanation:
Entropy is defined as the randomness in a system. In nature, a system tends to have high entropy. The higher the entropy , the spontaneous the reactions would be. As a system loses energy, it becomes more ordered and less random. Hence, as the reaction proceeds in a system, the system has higher energy/entropy and less order.
Hence, option c is correct
Explanation:
A chemical equilibrium is defined as the state of reaction in which the rate of forward reaction is equal to the rate of backward reaction.
When Q >
, then it means that the reaction is proceeding in the backward reaction. Whereas if Q <
, then it means that the reaction is proceeding in the forward direction. Hence, formation of products will be favored.
On the other hand, if Q =
, then it means reaction is at equilibrium.
At equilibrium, it is not necessary that the concentrations of products divided by the concentrations of reactants equals one.
Thus, we can conclude that the statement for a chemical system at equilibrium, the forward and reverse rates of reaction are equal, is correct.