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Alla [95]
3 years ago
15

For the following hypothetical reaction:

Chemistry
1 answer:
nlexa [21]3 years ago
4 0

 The  number  of   B that will be needed  to convert  5   moles  of A  into as many  moles of C as possible  is  20  moles

   Explanation

3A  + 12 B →  4 C

The  moles  of B  is calculated  using the mole ratio  of A  to B    from  equation above

that is the  moles  ratio  of  A:B  = 3 : 12

Therefore the  moles of  B = 5 x12/3 = 20 moles



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Consider the following reaction between mercury(II) chloride and oxalate ion:
siniylev [52]

Answer : The reaction rate will be, 1.9\times 10^{-4}M/s

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

2HgCl_2(aq)+C_2O_2^{4-}(aq)\rightarrow 2Cl^-(aq)+2CO_2(g)+HgCl_2(s)

Rate law expression for the reaction:

\text{Rate}=k[HgCl_2]^a[C_2O_2^{4-}]^b

where,

a = order with respect to HgCl_2

b = order with respect to C_2O_2^{4-}

Expression for rate law for first observation:

3.2\times 10^{-5}=k(0.164)^a(0.15)^b ....(1)

Expression for rate law for second observation:

2.9\times 10^{-4}=k(0.164)^a(0.45)^b ....(2)

Expression for rate law for third observation:

1.4\times 10^{-4}=k(0.082)^a(0.45)^b ....(3)

Expression for rate law for fourth observation:

4.8\times 10^{-5}=k(0.246)^a(0.15)^b ....(4)

Dividing 1 from 2, we get:

\frac{2.9\times 10^{-4}}{3.2\times 10^{-5}}=\frac{k(0.164)^a(0.45)^b}{k(0.164)^a(0.15)^b}\\\\9=3^b\\(3)^2=3^b\\b=2

Dividing 3 from 2, we get:

\frac{2.9\times 10^{-4}}{1.4\times 10^{-4}}=\frac{k(0.164)^a(0.45)^b}{k(0.082)^a(0.45)^b}\\\\2=2^a\\a=1

Thus, the rate law becomes:

\text{Rate}=k[HgCl_2]^1[C_2O_2^{4-}]^2

Now, calculating the value of 'k' by using any expression.

Putting values in above rate law, we get:

3.2\times 10^{-5}=k(0.164)^1(0.15)^2

k=8.7\times 10^{-3}M^{-2}s^{-1}

Now we have to determine the reaction rate when the concentration of HgCl_2 is 0.135 M and that of C_2O_2^{-4} is 0.40 M.

\text{Rate}=k[HgCl_2]^1[C_2O_2^{4-}]^2

\text{Rate}=(8.7\times 10^{-3})\times (0.135)^1\times (0.40)^2

\text{Rate}=1.9\times 10^{-4}M/s

Therefore, the reaction rate will be, 1.9\times 10^{-4}M/s

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If an element has two isotopes, what is the atomic mass if one of the isotopes has a mass of 15.000 amu and makes up 5.000% of t
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The atomic mass of element is the weighted average atomic mass of the element with respect to the abundance of the isotopes of that element 
atomic mass is the sum of the products of the mass of isotopes by their percentage abundance 
atomic mass = 15.000 amu x 5.000 % + 16.000 amu x 95.000 % 
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