Ice is less dense than water. Hydrogen bonding makes water more dense than when it is in the form of ice!
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Freeze drying<span> (or lyophilization) removes water from the ice cream by lowering the </span>air pressure<span> to a point where ice sublimates from a </span>solid<span> to a </span>gas<span>. The ice cream is placed in a </span>vacuum chamber<span> and frozen until the water </span>crystallizes<span>. The air pressure is lowered, creating a partial vacuum, forcing air out of the chamber; next heat is applied, </span>sublimating<span> the ice; finally a freezing coil traps the vaporized water. This process continues for hours, resulting in a freeze-dried ice cream slice. </span>
Answer : The final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.
Explanation :
As we know that:

At constant volume and temperature of gas, the pressure will be directly proportional to the number of moles of gas.
The relation between pressure and number of moles of gas will be:

where,
= initial pressure of gas = 24.5 atm
= final pressure of gas = 5.30 atm
= initial number of moles of gas = 1.40 moles
= final number of moles of gas = ?
Now put all the given values in the above expression, we get:


Therefore, the final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.
Unfortunately, you haven't shared any data list which would make braunly users able to help you. The only thing I can suggest you is to write the neutralization reactions, this can make you understand the calculations more or less clearly. Please, next time check your attachments carefully.