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Gelneren [198K]

4 years ago

14

The acid-dissociation constant, Ka, for benzoic acid is 6.5 × 10-5.

2 answers:

lina2011 [118]4 years ago

5 0

The correct anwerr is d

Gala2k [10]4 years ago

5 0

The correct answer of this one would be 1.5 x 10-10

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When a given reaction is conducted in a calorimeter, energy is absorbed from the surrounding water and results in a decrease in

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The potential energy of the products is higher than the potential energy of the reactants.

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Lisa [10]

We’d have to be very careful because if we had our skeletons on the outside it’d be very easy to injure ourselves

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3 years ago

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Positive Deviation from Raoult's Law occurs when the vapour pressure of component is greater than what is expected in Raoult's L

8090 [49]

Answer:

All of the above.

Explanation:

In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.

When a solution is non ideal then it shows positive or negative deviation.

Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is $P_A$ and vapour pressure of component B is $P_B$ .

$P^0_A$ = Vapour pressure of component A in pure form

$P^0_B$ = Vapour pressure of component B in pure form

$x_A$ =Mole fraction of component A

$x_B=$ =Mole fraction of component B

The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.

$P_A >P^0_A\cdot x_A$ , $P_B>P^0_B\cdot x_B$

Therefore, $P_A+P_B >P^0_A\cdot x_A+P^0_B \cdot x_B$

Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.

Hence, option a,b,c and d are true.

6 0

3 years ago

Phosgene (COCl2) is a toxic substance that forms readily from carbon monoxide and chlorine at elevated temperatures: CO(g) + Cl2

lapo4ka [179]

Answer: Concentration of $CO$ = 0.328 M

Concentration of $Cl_2$ = 0.328 M

Concentration of $COCl_2$ = 0.532 M

Explanation:

Moles of $CO$ and $Cl_2$ = 0.430 mole

Volume of solution = 0.500 L

Initial concentration of $CO$ and $Cl_2$ = $\frac{moles}{volume}=\frac{0.430}{0.500}=0.860M$

The given balanced equilibrium reaction is,

$CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)$

Initial conc. 0.860M 0.860M 0

At eqm. conc. (0.860-x) M (0.860-x) M (x) M

The expression for equilibrium constant for this reaction will be,

$K_c=\frac{[COCl_2]}{[CO][Cl_2]}$

Now put all the given values in this expression, we get :

$4.95=\frac{x}{(0.860-x)^2}$

By solving the term 'x', we get :

x = 0.532 M

Thus, the concentrations of $CO,Cl_2\text{ and }COCl_2$ at equilibrium are :

Concentration of $CO$ = (0.860-x) M =(0.860-0.532) M = 0.328 M

Concentration of $Cl_2$ = (0.860-x) M = (0.860-0.532) M = 0.328 M

Concentration of $COCl_2$ = x M = 0.532 M

3 0

3 years ago

Consider the reaction given below.

Drupady [299]

Answer:

<u>K = 0.167 s⁻¹</u>

Explanation:

<u>1) Rate law, at a given temperature:</u>

Since all the data are obtained at the same temperature, the equilibrium constant is the same.

Since only reactants A and B participate in the reaction, you assume that the form of the rate law is:

r = K [A]ᵃ [B]ᵇ

<u>2) Use the data from the table</u>

Since the first and second set of data have the same concentration of the reactant A, you can use them to find the exponent b:

r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

r₂ = (1.50)ᵃ (2.50)ᵇ = 2.50 × 10⁻¹ M/s

Divide r₂ by r₁: [ 2.50 / 1.50] ᵇ = 1 ⇒ b = 0

Use the first and second set of data to find the exponent a:

r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

r₃ = (3.00)ᵃ (1.50)ᵇ = 5.00 × 10⁻¹ M/s

Divide r₃ by r₂: [3.00 / 1.50]ᵃ = [5.00 / 2.50]

2ᵃ = 2 ⇒ a = 1

<u>3) Write the rate law</u>

r = K [A]¹ [B]⁰ = K[A]

This means, that the rate is independent of reactant B and is of first order respect reactant A.

<u>4) Use any set of data to find K</u>

With the first set of data

r = K (1.50 M) = 2.50 × 10⁻¹ M/s ⇒ K = 0.250 M/s / 1.50 M = 0.167 s⁻¹

Result: the rate constant is K = 0.167 s⁻¹

6 0

3 years ago