Answer:
B)−6,942 J
/mol
Explanation:
At constant temperature and pressure, you cand define the change in Gibbs free energy, ΔG, as:
ΔG = ΔH - TΔS
Where ΔH is enthalpy, T absolute temperature and ΔS change in entropy.
Replacing (25°C = 273 + 25 = 298K; 25.45kJ/mol = 25450J/mol):
ΔG = ΔH - TΔS
ΔG = 25450J/mol - 298K×108.7J/molK
ΔG = -6942.6J/mol
Right solution is:
<h3>B)−6,942 J
/mol</h3>
Democritus was the first person to theorize the existence of atoms.
Answer:
Zn =⇒ Zn+2(0.10) + 2e- (anode)
Zn+2(?M) + 2e- === Zn(s) (cathode)
Zn + Zn+2(?M) ===⇒ Zn+2(0.10) + Zn
E = E^o -0.0592 log Q; in this case E^o is zero.
E = - 0.0592 /n logQ where n is the number of electrons transferred, in this
case n = 2
23 mV x 1 volt/1000mv = 0.023 Volts
0.023 = -0.0592 / 2 log(0.10) / [Zn+2]
0.023 = -0.0296 { log 0.10 – log [Zn+2] }
0.023 = -0.0296{ -1 - log[Zn+2] }
0.023 = +0.0296 + 0.0296log[Zn+2]
-0.0066 = 0.0296log[Zn+2]
-0.22= log[Zn+2]
[Zn+2] = 10^-0.22 = 0.603 Molar
Answer:
Nitrobenzene is too deactivated (by the nitro group) to undergo a Friedel-Crafts alkylation.
Explanation:
The benzene ring in itself does not easily undergo electrophilic substitution reaction. Some groups activate or deactivate the benzene ring towards electrophilic substitution reactions.
-NO2 ia a highly deactivating substituent therefore, Friedel-Crafts alkylation of nitrobenzene does not take place under any conditions.
This reaction scheme is therefore flawed because Nitrobenzene is too deactivated (by the nitro group) to undergo a Friedel-Crafts alkylation.
