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3 years ago

Why is it significant that the color emitted from the hydrogen emission spectrum is not white?

Chemistry

1 answer:

just olya [345]3 years ago

8 0

The color emitted from a hydrogen spectrum is not white because only colors with certain energy levels can be observed.

Explanation:

White light is generally a combination of seven colors having different wavelengths from the range of 400nm to 700nm, with violet having the wavelength of 700nm and red having 400nm. This shows that white light cannot be given a separate wavelength.

During the hydrogen emission spectrum, the colors with higher wavelengths are observed in the emission and thus there is no white light.

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Text 8.7 Using the virial equation of state for hydrogen at 298 K given in problem 7 (text 8.6), calculate a. The fugacity of hy

gregori [183]

Answer:

a). P = 688 atm

b). P = 1083.04 atm

c).Δ G = 16.188 J/mol

Explanation:

a). Fugacity 'f' can be calculated from the following equations :

$\ln \frac{f}{P}=\int^P_0\left(\frac{Z-1}{P}\right) dP$

where, P = pressure , Z = compressibility

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$PV=R(1+6.4\times 10^{-4} P)$ ........(1)

Also, PV=ZRT for real gases .......(2)

∴ $ZRT=RT(1+6.4\times 10^{-4} P)$

$Z=1+6.4\times 10^{-4} P$

So from the fugacity equation ,

$\ln \frac{f}{P}=\int^P_0\left(\frac{1+6.4\times 10^{-4}P-1}{P}\right) dP$

$\ln \frac{f}{P}=\int^P_0\left(\frac{6.4\times 10^{-4}P}{P}\right) dP$

$\ln \frac{f}{P} = 6.4 \times 10^{-4} P$

$f=Pe^{6.4 \times 10^{-4} P}$

Putting the value of P = 500 atm in the above equation, we get,

f = 688 atm

b). Given f = 2P

$2P=PE^{6.4 \times 10^{-4}P}$

$2=E^{6.4 \times 10^{-4}P}$

$\ln 2 = 6.4 \times 10^{-4}P$

∴ P = 1083.04 atm

c). dG = Vdp -S dt at constant temperature, dT = 0

Therefore, dG = V dp

$\int^{G_2}_{G_1}dG =\int^{P_2}_{P_1}V dp$

$=\int^{P_2}_{P_1}\frac{RT}{P}\left(1+6.4 \times 10^{-4}P\right) dP$

$=\int^{P_2}_{P_1}RT\frac{dp}{P}+\int^{P_2}_{P_1}RT6.4 \times 10^{-4} dP$

$\Delta G=R[\ln\frac{P_2}{P_1}+6.4 \times 10^{-4}(P_2-P_1)]$

$\Delta G=8.314\times 298[\ln\frac{500}{1}+6.4 \times 10^{-4}(500-1)]$

Δ G = 16.188 J/mol

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How did thomsons experiment changes daltons atomic model

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