Draw the major organic substitution product(s) for (2R,3S)-2-bromo-3-methylpentane reacting with the given nucleophile. Indicate
the stereochemistry, including H\'s, at each stereogenic center. Omit any byproducts.
1 answer:
Answer:
The final product of the reaction is (<em>2S,3S</em>)-2-ethoxy-3-methylpentane.
Explanation:
The given reaction undergoes mechanism in which the nucleophile attacks the backside and it is substituted by the elimination of bromine.
Due to the backside attack of nucleophile , the inverse in stereo-chemistry is observed.
After the substitution of ethoxy group, the configuration is assigned according to the priority it shows clock wise direction(R) - configuration.
When hydrogen faces the front side , it results shows inverse configuration i.e, S- configuration.
The chemical reaction is as follows.
You might be interested in
Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp =
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp =
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 =
0.0104 +
- 200 = 0
Resolving the second degree equation:
=
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer:
Explanation:
Hello,
In this case, for the equilibrium condition, the equilibrium constant is defined via the law of mass action, which states that the division between the concentrations of the products over the concentration of the reactants at equilibrium equals the equilibrium constant, for the given reaction:
The suitable equilibrium constant turns out:
Or in terms of the initial equilibrium constant:
Since the second reaction is a doubled version of the first one.
Best regards.