Answer:
1.71x10²⁷
Explanation:
If we sum 1/2 of (3) + 1/2 of (1):
1/2 (3.) C(s) + 1/2O₂(g) ⇌ CO(g), K₃ = √2.10×10⁴⁷ = 4.58x10²³
1/2 (1) 1/2CO₂(g) + 3/2H₂(g) ⇌ 1/2CH₃OH(g) + 1/2H₂O(g), K₁ = √1.40×10² = 11.8
C(s) + 1/2O₂(g) +<u> 1/2CO₂(g) </u>+<u> 3/2H₂(g</u>) ⇌ 1/2CH₃OH(g) + <u>1/2H₂O(g)</u> + <u>CO(g)</u>
K' = 4.58x10²³ * 11.8 = 5.42x10²⁴
+1/2 (2):
<u>1/2 CO(g)</u> +<u> 1/2H₂O(g)</u> ⇌<u> 1/2CO₂(g)</u> + <u>1/2H₂</u> (g), K = √1.00×10⁵ = 316.2
C(s) + 1/2O₂(g) + H₂(g) ⇌ 1/2 CHO₃H(g) + 1/2CO(g)
K'' = 5.42x10²⁴* 316.2 =
<h3>1.71x10²⁷</h3>
Answer:
-3135.47 kJ/mol
Explanation:
Step 1: Write the balanced equation
C₆H₆(l) + 7.5 O₂(g) ⇒ 6 CO₂(g) + 3 H₂O(g)
Step 2: Calculate the standard enthalpy change of the reaction (ΔH°r)
We will use the following expression.
ΔH°r = ∑np × ΔH°f(p) - ∑nr × ΔH°f(r)
where,
n: moles
ΔH°f: standard enthalpies of formation
p: products
r: reactants
ΔH°r = 6 mol × ΔH°f(CO₂(g)) + 3 mol × ΔH°f(H₂O(g)) - 1 mol × ΔH°f(C₆H₆(l)) - 7.5 mol × ΔH°f(O₂(g))
ΔH°r = 6 mol × (-393.51 kJ/mol) + 3 mol × (-241.82 kJ/mol) - 1 mol × (48.95 kJ/mol) - 7.5 mol × 0 kJ/mol
ΔH°r = -3135.47 kJ
Since this enthalpy change is for 1 mole of C₆H₆(l), we can express it as -3135.47 kJ/mol.
Answer:
(CH3)3C^+ + OH^- --------> (CH3)3COH
Explanation:
This reaction has to do with SN1 reaction of alkyl halides. Here tert-butanol is formed from tert-butyl bromide.
The first step in the reaction is the formation of a carbocation. This is a unimolecular reaction. The rate of reaction depends on the concentration of the alkyl halide. This is a slow step and thus the rate determining step in the mechanism.
(CH3)3CBr -------> (CH3)3C^+ + Br^-
The second step is a fast step and it completes the reaction mechanism. It is a bimolecular reaction as follows;
(CH3)3C^+ + OH^- --------> (CH3)3COH
Ksp - solubility product constant is equivalent to equilibrium constant, except this constant is used to determine the solubility of ions of a solid in a solution.
ksp is the product of the soluble ions in the compound. Higher the ksp value, higher the degree of solubility.
ZnCO₃ (s) ---> Zn²⁺ (aq) + CO₃²⁻ (aq)
n n
ksp = [Zn²⁺][CO₃²⁻]
In the equation equal amounts of ions Zn²⁺ and CO₃²⁻ ions are soluble.
amount of ions soluble = n
ksp is therefore equal to;
ksp = n x n
ksp = n²
ksp = 1 * 10⁻¹⁰ M
therefore
1 * 10⁻¹⁰ M = n²
n = 1 x 10⁻⁵ M
therefore concentration of CO₃²⁻ = 1 x 10⁻⁵ M
