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nikitadnepr [17]
3 years ago
5

Which of the following processes have a ΔS > 0? A. N2(g) + 3 H2(g) → 2 NH3(g) B. Na2CO3(s) + H2O(g) + CO2(g) → 2 NaHCO3(s) C.

CH3OH(l) → CH3OH(s) D. All of these processes have a ΔS > 0. E. CH4(g) + H2O (g) → CO(g) + 3 H2(g)
Chemistry
1 answer:
Olegator [25]3 years ago
4 0

Answer:

ΔS > 0 only for choice E: CH4(g) + H2O (g) → CO(g) + 3 H2(g)

Explanation:

Our strategy in this question is to use the trend in entropies :

S (solids)  less than S (liquids) less than S (gases)

Also we have to look for the  molar quanties involved of each state and their change to answer the question:

A. N2(g) + 3 H2(g) → 2 NH3(g)

Here we have 4 moles gases going to 2 moles of products, so the change in entropy is negative.

B. Na2CO3(s) + H2O(g) + CO2(g) → 2 NaHCO3(s)

The change in entropy is negative since we have 2 mol gases in the reactants and zero in the products.

C. CH3OH(l) → CH3OH(s)

A liquid has a higher entropy than a solid so ΔS is negative

D. False see A,B,C

E. The change in moles of gases is 4 - 2= 2, therefore  ΔS is greater than O.

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1. 4-ethyl-1-heptene

2. 6-ethyl-2-octene

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Explanation:

The compounds are named according to IUPAC rules.

Compound 1:

  • Identify the longest carbon chain. This chain is called the parent chain.
  • Identify all of the substituents (groups appending from the parent chain).
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  • The double bond between C1 and C2, so take no. 1 and add the suffix ene to hept "1-heptene".
  • The ethyl group is the alkyl substituent on position 4.
  • So the name is 4-ethyl-1-heptene.

Compound 2:

  • Identify the longest carbon chain. This chain is called the parent chain.
  • Identify all of the substituents (groups appending from the parent chain).
  • The parent chain is numbered so that the multiple bonds have the lowest numbers (double has the priority over alkyl substituents).
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  • The double bond between C2 and C3, so take no. 2 and add the suffix ene to oct "2-octene".
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Compound 3:

  • Identify the longest carbon chain. This chain is called the parent chain.
  • Identify all of the substituents (groups appending from the parent chain), there is no substituents.
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  • The longest chain contains 4 carbon atoms, so taken the name but.
  • The triple bond between C1 and C2, so take no. 1 and add the suffix yne to but "1-butyne".
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