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Nata [24]
3 years ago
15

Lead(II) nitrate and ammonium iodide react to form lead(II) iodide and ammonium nitrate according to the reaction Pb(NO3)2(aq)+2

NH4I(aq)⟶PbI2(s)+2NH4NO3(aq) What volume of a 0.250 M NH4I solution is required to react with 121 mL of a 0.360 M Pb(NO3)2 solution? volume: mL How many moles of PbI2 are formed from this reaction? moles: mol PbI2
Chemistry
1 answer:
Setler79 [48]3 years ago
7 0

Answer:

a) volume of ammonium iodide required =349 mL

b) the moles of lead iodide formed = 0.0436 mol

Explanation:

The reaction is:

Pb(NO_{3})_{2}+2NH_{4}I -->PbI_{2}+2NH_{4}NO_{3}

It shows that one mole of lead nitrate will react with two moles of ammonium iodide to give one mole of lead iodide.

Let us calculate the moles of lead nitrate taken in the solution.

Moles=molarityX volume (L)

Moles of lead nitrate = 0.360 X 0.121 =0.0436 mol

the moles of ammonium iodide required = 2 X0.0436 = 0.0872 mol

The volume of ammonium iodide required will be:

volume=\frac{moles}{molarity}=\frac{0.0872}{0.250}=0.349L=349mL

the moles of lead iodide formed = moles of lead nitrate taken = 0.0436 mol

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1. The balanced equation is given below:

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2b. Sn is reduced.

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1. Balanced equation for the reaction between tin (Sn) metal and aqueous hydrochloric acid (HCl) to produce tin(II) chloride (SnCl₂) and hydrogen gas (H₂).

This is illustrated below:

Sn (s) + HCl (aq) –> SnCl₂ (aq) + H₂ (g)

There are 2 atoms of Cl on the right side and 1 atom on the left side. It can be balance by putting 2 in front of HCl as shown below:

Sn (s) + 2HCl (aq) –> SnCl₂ (aq) + H₂ (g)

Now, the equation is balanced

2. Determination of the element that is oxidize and reduced.

This can be obtained as follow:

We shall determine the change in oxidation number of each element.

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a. The oxidation number of H is always +1 except in hydrides where it is –1.

b. The oxidation state of Cl is always –1.

Sn (s) + 2HCl (aq) –> SnCl₂ (aq) + H₂ (g)

For Tin (Sn):

Sn = 0

SnCl₂ = 0

Sn + 2Cl = 0

Cl = – 1

Sn + 2(–1) = 0

Sn – 2 = 0

Collect like terms

Sn = 0 + 2

Sn = +2

Therefore, the oxidation number of Tin (Sn) changes from 0 to +2

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H = +1

H₂ = 0

The oxidation number of H changes from +1 to 0

For Cl:

Cl is always –1. Therefore no change.

Summary:

Element >>Change in oxidation number

Sn >>>>>>>From 0 to +2

H >>>>>>>>From +1 to 0

Cl >>>>>>>No change

Therefore,

Sn is reduced since its oxidation number increased from 0 to +2.

H is oxidized since it oxidation number reduced from +1 to 0

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2 years ago
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