Answer:
6.574 g NaF into 300ml (0.25M HF) => Bfr with pH ~3.5
Explanation:
For buffer solution to have a pH-value of 3.5 the hydronium ion concentration [H⁺] must be 3.16 x 10⁻⁴M ( => [H⁺] = 10^-pH = 10⁻³°⁵ =3.16 x 10⁻⁴M).
Addition of NaF to 300ml of 0.25M HF gives a buffer solution. To determine mass of NaF needed use common ion analysis for HF/NaF and calculate molarity of NaF, then moles in 300ml the x formula wt => mass needed for 3.5 pH.
HF ⇄ H⁺ + F⁻; Ka = 6.6 x 10⁻⁴
Ka = [H⁺][F⁻]/[HF] = 6.6 x 10⁻⁴ = (3.16 x 10⁻⁴)[F⁻]/0.25 => [F⁻] = (6.6 x 10⁻⁴)(0.25)/(3.16x10⁻⁴) = 5.218M in F⁻ needed ( = NaF needed).
For the 300ml buffer solution, moles of NaF needed = Molarity x Volume(L)
= (5.218M)(0.300L) = 0.157 mole NaF needed x 42 g/mole = 6.574 g NaF needed.
Check using the Henderson - Hasselbalch Equation...
pH = pKa + log ([Base]/[Acid]); pKa (HF) = 3.18
Molarity of NaF = (6.572g/42g/mole)/(0.300 L soln) = 0.572M in NaF = 0.572M in F⁻.
pH = 3.18 + log ([0.572]/[0.25]) ≅ 3.5.
One can also back calculate through the Henderson -Hasselbalch Equation to determine base concentration, moles NaF then grams NaF.
Organic Chemistry is a sub-unit of chemistry which refers to the scientific study of carbon compounds. It focuses on the structure, properties, composition, reactions, of carbon containing compounds.
Example of carbon compounds include salt, alcohol, ethane, methane, butane, benzene, hexane and more.
Answer:
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Explanation:
The lower you go, the more acidic. The higher you go, the more alkaline. Your answer would most likely be 6.
Answer:
H₂²⁺(aq) + O₂²⁻(aq) + SO₃²⁻(aq) → SO²⁻₄(aq) + H₂O(l)
Explanation:
H₂²⁺(aq) + O₂²⁻(aq) + Mg²⁺(aq) + SO₃²⁻(aq) → Mg²⁺(aq) + SO²⁻₄(aq) + H₂O(l)
A careful observation of the equation above, shows that the equation is already balanced.
To obtain the net ionic equation, we simply cancel Mg²⁺ from both side of the equation as shown below:
H₂²⁺(aq) + O₂²⁻(aq) + SO₃²⁻(aq) → SO²⁻₄(aq) + H₂O(l)