I really hope and think it’s E
From Q = mcΔΤ, the specific heat capacity, c, of the metal that was cooled is c = Q/mΔT = (-769 J)/(46.4 g)(30.0 °C - 101.0 °C) = 0.233 J/g °C. From the table, it appears that this is the specific heat capacity of silver. So, the metal is most like silver.
Note: The value for Q was written as a negative value in the equation as heat energy was given off by the metal when the metal was cooled (from the metal’s point of view, it’s losing heat energy).
Answer : The final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.
Explanation :
As we know that:

At constant volume and temperature of gas, the pressure will be directly proportional to the number of moles of gas.
The relation between pressure and number of moles of gas will be:

where,
= initial pressure of gas = 24.5 atm
= final pressure of gas = 5.30 atm
= initial number of moles of gas = 1.40 moles
= final number of moles of gas = ?
Now put all the given values in the above expression, we get:


Therefore, the final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.