1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Vanyuwa [196]
3 years ago
6

Consider the formation of [Ni(en)3]2+ from [Ni(H2O)6]2+. The stepwise ΔG∘ values at 298 K are ΔG∘1 for first step=−42.9 kJ⋅mol−1

ΔG∘2 for second step=−35.8 kJ⋅mol−1 ΔG∘3 for third step=−24.3 kJ⋅mol−1 Calculate the overall formation constant (Kf) for the complex [Ni(en)3]2+.
Chemistry
1 answer:
timurjin [86]3 years ago
7 0

Answer:

kf = 1.16 x 10¹⁸

Explanation:

Step 1: [Ni(H₂O)₆]²⁺  + 1en → [Ni(H₂O)₄(en)]²⁺  ΔG°1 = -42.9 kJmol⁻¹

Step 2: [Ni(H₂O)₄(en)]²⁺  + 1en → [Ni(H₂O)₂(en)₂]²⁺  ΔG°2 = -35.8 kJmol⁻¹

Step 3: [Ni(H₂O)₂(en)₂]²⁺ + 1en →  [Ni(en)₃]²⁺  ΔG°3 = -24.3 kJmol⁻¹

________________________________________________________

Overall reaction: [Ni(H₂O)₆]²⁺  + 3en → [Ni(en)₃]²⁺  ΔG°r

ΔG°r = ΔG°1 + ΔG°2 + ΔG°3

ΔG°r = -42.9 - 35.8 - 24.3

ΔG°r = -103.0 kJmol⁻¹

ΔG°r = -RTlnKf

-103,000 Jmol⁻¹ =  - 8.31 J.K⁻¹mol⁻¹ x 298 K x lnKf

kf = e ^(-103,000/-8.31x298)

kf = e ^41.59

kf = 1.16 x 10¹⁸

You might be interested in
Write the possible sets of quantum numbers of l=3
kykrilka [37]

Answer:

Explanation:

There are four quantum numbers:

Principal quantum number (n)

Azimuthal quantum number (l)

Magnetic quantum number (ml)

Spin quantum number (ms)

All these four quantum numbers gives complete information about an electron like its spin, shells, subshells and orbitals.

For example:

If l=3 than possible sets of quantum numbers are:

Azimuthal quantum number (l)

The azimuthal quantum number describe the shape of orbitals. Its value for s, p, d, f... are 0, 1, 2, 3. For l=3

(n-1)

4-1 = 3

it means principle quantum is 4 and electron is present in f subshell.

Magnetic quantum number (ml)

It describe the orientation of orbitals. Its values are -l to +l. For l=3  the ml will be -3 -2 -1 0 +1 +2 +3.

Spin quantum number (ms)

The spin quantum  number tells the spin of electron either its clock wise (+1/2) or anti clock wise (-1/2).

If the electron is added in full empty orbital its spin will be +1/2 because it occupy full empty. If electron is already present and another electron is added then its spin will be -1/2.

4 0
3 years ago
Which of the following is the smallest volume? 500 mL 2,500 cm3 5.5 x 10-1 L 25 m3
Anni [7]
500 ml is the answer
6 0
3 years ago
Please help this is due today which ones are reactive and which arent?​
BARSIC [14]

Answer:

I' really don't know I'm sorry

4 0
3 years ago
If you dissolve 50.0 grams of potassium bromide in 100.0g of water what is the mass percent of the resultant solution?
tatiyna
Mass percent= grams solute/ grams of solution x 100

Mass Percent= (50/ 150)x100= 33.3%
7 0
3 years ago
What happens if the metal you throw in is MORE REACTIVE than the<br> metal ion in solution?
IRISSAK [1]
A displacement reaction Would occur in this situation
6 0
3 years ago
Other questions:
  • Disappearance of NO in ...- Help!!!? The following data were collected for the rate of disappearance of NO in the reaction 2 NO(
    9·1 answer
  • 1.00 M aqueous solution of NaOH, a 0.50 M aqueous solution of H2SO4 and a coffee cup calorimeter were allowed to stand at a room
    13·2 answers
  • A system of 1515 particles, each of which is either an electron or a proton, has a net charge of −6.032×10−17
    10·1 answer
  • Balanced equation of sulphur dioxide ​
    11·1 answer
  • Which extinction factors do you think cause the most extinctions? Why?
    8·2 answers
  • Examine the diagram of the cell cycle. Which label identifies the stage in which the DNA is copied and the cell grows? W X Y Z
    9·2 answers
  • 6) The following questions refer to F2 and Cl2.
    6·1 answer
  • Pure gold has a density of 19.3 g/cm³. if it is made into a crown. what will be the density of the crown? how can you find out i
    11·1 answer
  • He density of water is 1 g/mL.
    14·1 answer
  • The substance whose lewis structure shows three covalent bonds is
    15·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!