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zalisa [80]
3 years ago
11

A 52.0-mL volume of 0.35 M CH3COOH (Ka=1.8×10−5) is titrated with 0.40 M NaOH. Calculate the pH after the addition of 23.0 mL of

NaOH.
Chemistry
1 answer:
Rus_ich [418]3 years ago
6 0
<span> 52.0ml of 0.35M CH3COOH : 0.052 L(0.35M) = .0182 mol of CH3COOH. 
</span>
<span>31.0ml of 0.40M NaOH : .031 L(0.40M) = .0124 mol of NaOH. 
</span>
<span>After the  reaction, .0124 Mol CH3COO- is generated and .058 mol CH3COOH is left un-reacted. The concentration would be 12.4/V and 5.8/V, respectively. Therefore:

 </span>
<span>pH = -log([H+]) = -log(Ka*[CH3COOH]/[CH3COO-]) </span>
<span>= -log(1.8x10^-5*5.8/12.4) = 5.07</span>
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